MSDS LIST: | MSDS Formaldehyde CAS 50-00-0 MSDS * Aldehyde formique * Aldehyd mravenci * Aldeide formica * BFV * Fannoform * Formaldehyde * Formaldehyd * Formaldehyde, gas * Formalin * Formalin 40 * Formalina * Formaline * Formalin-loesungen * Formalith * Formic aldehyde * Formol * FYDE * Lysoform * Methaldehyde * Methanal * Methyl aldehyde * Methylene oxide * Morbicid * NCI-C02799 * Oplossingen * Oxomethane * Oxymethylene * Paraform * RCRA waste number U122 * Superlysoform
50-00-0 SYNONYMS : * Aldehyde formique * Aldehyd mravenci * Aldeide formica * BFV * Fannoform * Formaldehyde * Formaldehyd * Formaldehyde, gas * Formalin * Formalin 40 * Formalina * Formaline * Formalin-loesungen * Formalith * Formic aldehyde * Formol * FYDE * Lysoform * Methaldehyde * Methanal * Methyl aldehyde * Methylene oxide * Morbicid * NCI-C02799 * Oplossingen * Oxomethane * Oxymethylene * Paraform * RCRA waste number U122 * Superlysoform *** CHEMICAL IDENTIFICATION *** RTECS NUMBER : LP8925000 CHEMICAL NAME : Formaldehyde CAS REGISTRY NUMBER : 50-00-0 OTHER CAS REGISTRY NOS. : 8005-38-7 8006-07-3 8013-13-6 112068-71-0 LAST UPDATED : 199806 DATA ITEMS CITED : 216 MOLECULAR FORMULA : C-H2-O MOLECULAR WEIGHT : 30.03 WISWESSER LINE NOTATION : VHH COMPOUND DESCRIPTOR : Agricultural Chemical Tumorigen Mutagen Reproductive Effector Human Primary Irritant SYNONYMS/TRADE NAMES : * Aldehyde formique * Aldehyd mravenci * Aldeide formica * BFV * Fannoform * Formaldehyde * Formaldehyd * Formaldehyde, gas * Formalin * Formalin 40 * Formalina * Formaline * Formalin-loesungen * Formalith * Formic aldehyde * Formol * FYDE * Lysoform * Methaldehyde * Methanal * Methyl aldehyde * Methylene oxide * Morbicid * NCI-C02799 * Oplossingen * Oxomethane * Oxymethylene * Paraform * RCRA waste number U122 * Superlysoform *** HEALTH HAZARD DATA *** ** SKIN/EYE IRRITATION DATA ** TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Human DOSE/DURATION : 150 ug/3D (Intermittent) REACTION SEVERITY : Mild REFERENCE : 85DKA8 "Cutaneous Toxicity, Proceedings of the 3rd Conference, 1976," Drill, V.A., and P. Lazar, eds., New York, Academic Press, Inc. 1977 Volume(issue)/page/year: -,127,1977 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Human DOSE/DURATION : 4 ppm/5M REFERENCE : IAPWAR International Journal of Air and Water Pollution. (London, UK) V.4(1-4), 1961. For publisher information, see ATENBP. Volume(issue)/page/year: 4,79,1961 TYPE OF TEST : Non-standard exposure ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Human DOSE/DURATION : 1 ppm/6M REACTION SEVERITY : Mild REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 44,463,1983 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 2 mg/24H REACTION SEVERITY : Severe REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,264,1986 TYPE OF TEST : Open irritation test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 540 mg REACTION SEVERITY : Mild REFERENCE : UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 4/21/1967 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 50 mg/24H REACTION SEVERITY : Moderate REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 21,369,1972 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 750 ug/24H REACTION SEVERITY : Severe REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,264,1986 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 750 ug REACTION SEVERITY : Severe REFERENCE : AJOPAA American Journal of Ophthalmology. (Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611) Series 3: V.1- ...
http://www.chemcas.com/msds/cas/msds57/50-00-0.asp | | | | MSDS PAGE: MSDS 50-00-0 CAS 1-TOSYL-4-PHENYL-4-CARBOXY PIPERIDINE
50-00-0 SYNONYMS : **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| |----------------|--------------------------------------|----------|-----------| | 50-00-0 |This is a test | | 200-001-8 | |----------------|--------------------------------------|----------|-----------| | 39633-82-4 | | 99+ | 254-548-2 | +----------------+--------------------------------------+----------+-----------+ Text for R-phrases: see Section 16 Hazard Symbols: XN T+ N Risk Phrases: 20/21 22 45 46 49 50 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Harmful by inhalation and in contact with skin. Harmful if swallowed. May cause cancer. May cause heritable genetic damage. May cause cancer by inhalation. Very toxic to aquatic organisms. Potential Health Effects The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with the skin or eyes and to prevent inhalation. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Not available. Skin: Not available. Ingestion: Not available. Inhalation: Not available. Notes to Physician: **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: Not available. Extinguishing Media: Not available. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Not available. **** SECTION 7 - HANDLING and STORAGE **** Handling: Not available. Storage: Not available. **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION **** Engineering Controls: Personal Protective Equipment Eyes: Not available. Skin: Not available. Clothing: Not available. Respirators: Not available. **** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES **** Physical State: Not available. Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: Molecular Weight: **** SECTION 10 - STABILITY AND REACTIVITY **** Chemical Stability: Not available. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Not available. Hazardous Decomposition Products: Not available. Hazardous Polymerization: Not available. **** SECTION 11 - TOXICOLOGICAL INFORMATION **** RTECS#: CAS# 50-00-0: LP8925000 CAS# 39633-82-4 unlisted. LD50/LC50: CAS# 50-00-0: Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, eye: 750 ug Severe; Draize test, rabbit, eye: 10 mg Severe; Draize test, rabbit, eye: 37% Severe; Draize test, rabbit, skin: 2 mg/24H Severe; Draize test, rabbit, skin: 50 mg/24H Moderate; Inhalation, mouse: LC50 = 454 mg/m3/4H; Inhalation, mouse: LC50 = 505 mg/m3/2H; Inhalation, rat: LC50 = 203 mg/m3; Inhalation, rat: LC50 = 578 mg/m3/2H; Inhalation, rat: LC50 = 250 ppm/2H; Oral, mouse: LD50 = 42 mg/kg; Oral, mouse: LD50 = 385 mg/kg; Oral, mouse: LD50 = 500 mg/kg; Oral, rat: LD50 = 100 mg/kg; Oral, rat: LD50 = 500 mg/kg; Skin, rabbit: LD50 = 270 uL/kg; Skin, rabbit: LD50 = 270 mg/kg. CAS# 39633-82-4. Carcinogenicity: This is a test - ACGIH: A2 - Suspected Human Carcinogen California: carcinogen, initial date 1/1/88 (gas) NTP: Suspect carcinogen IARC: Group 2A carcinogen - Not listed by ACGIH, IARC, or NTP. See actual entry in RTECS for complete information. **** SECTION 12 - ECOLOGICAL INFORMATION **** **** SECTION 13 - DISPOSAL CONSIDERATIONS **** Dispose of in a manner consistent with federal, state, and local regulations. **** SECTION 14 - TRANSPORT INFORMATION **** IATA Not...
http://www.chemcas.com/material/cas/archive/50-00-0_v14.asp | | | | MSDS PAGE: MSDS 50-00-0 CAS Formaldehyde solution 37% Formalin.
50-00-0 SYNONYMS : Formalin. **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| |----------------|--------------------------------------|----------|-----------| | 50-00-0 |Formaldehyde | 37 | 200-001-8 | |----------------|--------------------------------------|----------|-----------| | 67-56-1 |Methyl alcohol | 15 | 200-659-6 | |----------------|--------------------------------------|----------|-----------| | 7732-18-5 |Water | 48 | 231-791-2 | +----------------+--------------------------------------+----------+-----------+ Text for R-phrases: see Section 16 Hazard Symbols: T C Risk Phrases: 10 23/24/25 34 43 45 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Flammable. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. May cause sensitization by skin contact. May cause cancer. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Ingestion: May be fatal or cause blindness if swallowed. May cause liver and kidney damage. May cause burns to the digestive tract. May cause central nervous system depression. Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest. Chronic: Contains formaldehyde which can cause cancer in humans. There is sufficient evidence that formaldehyde causes nasopharyngeal cancer in humans, a rare cancer in developed countries. There is limited evidence that formaldehyde causes cancer of the nasal cavity and paranasal sinuses and strong but not sufficient evidence for leukemia. Repeated exposure may cause skin discoloration and thickening and nail decay. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Skin: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Informat...
http://www.chemcas.com/material/cas/archive/50-00-0_v3.asp | | | | MSDS PAGE: MSDS 50-00-0 CAS Formaldehyde solution (20%) None.
50-00-0 SYNONYMS : None. **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| |----------------|--------------------------------------|----------|-----------| | 50-00-0 |Formaldehyde | 20 | 200-001-8 | |----------------|--------------------------------------|----------|-----------| | 7732-18-5 |Water | 80 | 231-791-2 | +----------------+--------------------------------------+----------+-----------+ Text for R-phrases: see Section 16 Hazard Symbols: T Risk Phrases: 20/21/22 36/37/38 43 45 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. May cause cancer. Potential Health Effects Eye: Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Vapors may cause eye irritation. Lachrymator (substance which increases the flow of tears). Skin: Causes skin irritation. Harmful if absorbed through the skin. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. In severe cases may produce blistering, scaling and cracking. Irritant dermatitis results from the direct injury to the skin and is characterized by redness and thickening of the affected areas. Ingestion: Harmful if swallowed. May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. Inhalation: Harmful if inhaled. Effects may be delayed. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Chronic: Contains formaldehyde which can cause cancer in humans. There is sufficient evidence that formaldehyde causes nasopharyngeal cancer in humans, a rare cancer in developed countries. There is limited evidence that formaldehyde causes cancer of the nasal cavity and paranasal sinuses and strong but not sufficient evidence for leukemia. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. **** SECTION 7 - HANDLING and STORAGE **** Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reus...
http://www.chemcas.com/material/cas/archive/50-00-0_v4.asp | | | | MSDS PAGE: MSDS 50-00-0 CAS Decalcifying solution II None.
50-00-0 SYNONYMS : None. **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| |----------------|--------------------------------------|----------|-----------| | 50-00-0 |Formaldehyde | 4.0 | 200-001-8 | |----------------|--------------------------------------|----------|-----------| | 64-18-6 |Formic acid | 10-15 | 200-579-1 | |----------------|--------------------------------------|----------|-----------| | 7732-18-5 |Water | Balance | 231-791-2 | +----------------+--------------------------------------+----------+-----------+ Text for R-phrases: see Section 16 Hazard Symbols: T C Risk Phrases: 34 45 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Causes burns. May cause cancer. Potential Health Effects Eye: Causes eye burns. May cause chemical conjunctivitis and corneal damage. Skin: Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects. Inhalation: Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects. Chronic: Contains formaldehyde which can cause cancer in humans. There is sufficient evidence that formaldehyde causes nasopharyngeal cancer in humans, a rare cancer in developed countries. There is limited evidence that formaldehyde causes cancer of the nasal cavity and paranasal sinuses and strong but not sufficient evidence for leukemia. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. **** SECTION 7 - HANDLING and STORAGE **** Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use only with adequate ventilation. Storage: Keep container closed when not in use. **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL ...
http://www.chemcas.com/material/cas/archive/50-00-0_v8.asp | | | | MSDS PAGE: MSDS 50-00-0 CAS Bouins fixative None.
50-00-0 SYNONYMS : None. **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| |----------------|--------------------------------------|----------|-----------| | 50-00-0 |Formaldehyde | 4.0 | 200-001-8 | |----------------|--------------------------------------|----------|-----------| | 64-19-7 |Acetic acid | 2.0 | 200-580-7 | |----------------|--------------------------------------|----------|-----------| | 88-89-1 |Picric acid | 1.0 | 201-865-9 | |----------------|--------------------------------------|----------|-----------| | 7732-18-5 |Water | Balance | 231-791-2 | +----------------+--------------------------------------+----------+-----------+ Text for R-phrases: see Section 16 Hazard Symbols: T Risk Phrases: 20/21/22 43 45 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. May cause sensitization by skin contact. May cause cancer. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May be harmful if absorbed through the skin. Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Contains formaldehyde which can cause cancer in humans. There is sufficient evidence that formaldehyde causes nasopharyngeal cancer in humans, a rare cancer in developed countries. There is limited evidence that formaldehyde causes cancer of the nasal cavity and paranasal sinuses and strong but not sufficient evidence for leukemia. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. **** SECTION 7 - HANDLING and STORAGE **** Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. Use only with adequate ventilation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION **** Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyew...
http://www.chemcas.com/material/cas/archive/50-00-0_v9.asp | | | | MSDS PAGE: CAS 50-00-0 MSDS 1448-92_busan_1024_6_2_2006_2_50_04_pm.asp
50-00-0 File Name : 1448-92_busan_1024_6_2_2006_2_50_04_pm.asp BUCKMAN LABORATORIES, INC. MATERIAL SAFETY DATA SHEET BUSAN 1024 Revision date: 3/2/2005 Phone 1-800-BUCKMAN Buckman Laboratories, Inc. 1256 North McLean Boulevard 24 Hour Emergency Phone: (901) 767-2722 Memphis, TN 38108 SECTION 1 OSHA HAZARD CLASSIFICATIONS Irritating to eyes. SECTION 2 HAZARDOUS COMPONENTS Chemical Name CAS Number % by Weight TLV Formaldehyde 50-00-0 0.2 ACGIH (United States). CEIL: 0.37 mg/m3 CEIL: 0.3 ppm OSHA (United States). TWA: 0.75 ppm STEL: 2 ppm Buckman Laboratories reports the component(s) listed above as known OSHA hazardous material(s) contained in this product. SECTION 3 FIRST AID INFORMATION Eye Flush immediately with copious amounts of tap water or normal saline (minimum of 15 Exposure: minutes). Take exposed individual to a health care professional, preferably an ophthalmologist, for further evaluation. Skin Wash exposed area with plenty of water. Repeat washing. Remove contaminated clothing and Exposure: wash thoroughly before reuse. If irritation persists consult a health care professional. Inhalation: If exposure by inhalation is suspected, immediately move exposed individual to fresh air. If individual experiences nausea, headache, dizziness, has difficulty in breathing or is cyanotic, seek a health care professional immediately. Ingestion: DO NOT INDUCE VOMITING. Rinse with copious amounts of water or milk, first. Irrigate the esophagus and dilute stomach contents by slowly giving one (1) to two (2) glasses of water or milk. Avoid giving alcohol or alcohol related products. In cases where the individual is semi- comatose, comatose or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In case of intentional ingestion of the product seek medical assistance immediately; take individual to nearest medical facility. BUSAN 1024 USA Page 2 BUSAN 1024 Last revision ... 3/2/2005 SECTION 4 PRIMARY ROUTES OF EXPOSURE 1. Effects from Acute Exposure: Eye Slightly hazardous in case of eye contact (irritant). Exposure: Skin Non-irritant for skin. Non-sensitizer for skin. Exposure: Inhalation: Slightly hazardous in case of inhalation. Effects will depend on concentration and length of time of exposure. Ingestion: Ingestion is not expected to be a primary route of exposure. 2. Effects from Chronic Exposure: This product has tested negative in both animal and human sensitization tests. Birth defects are unlikely, as animal tests on the active ingredient were negative. SECTION 5 Toxicological Information Acute Effects: Acute Oral (LD50) = >5000 mg/kg Rat Acute Dermal (LD50) = >2000 mg/kg Rabbit Acute Inhalation (LC50) = >3.2 mg/l ( 4 hours) Rat Irritant / Sensitization Effects: Slightly hazardous in case of eye contact (irritant). Non-irritant for skin. Non-sensitizer for skin. Slightly hazardous in case of inhalation. Effects will depend on concentration and length of time of exposure. Carcinogenic Potential: Not tested by Buckman Laboratories. Contains a small amount of formaldehyde, which has been proven to be a carcinogen. Target Organs Effects: May cause damage to the following organs: upper respiratory tract, skin, eyes. Other Health Effects: Inhalation toxicity was conducted under misting conditions. Normal use of this product under non-misting conditions should not present an occupational hazard. This product has tested negative in both animal and human sensitization tests. Birth defects are unlikely, as animal tests on the active ingredient were negative. SECTION 6 Environmental Toxicological Information LC50 = 136 mg/l 48 hours Daphnia magna LC50 = 337 mg/l 96 hours Bluegill sunfish. LC50 = 624 mg/l 96 hours Rainbow trout. BUSAN 1024 USA Page 3 BUSAN 1024 Last revision ... 3/2/2005 SECTION 7 Physical and Chemical Properties Appearance .............................. Clear, colorless. liquid Odor ........................................... Alcohol. (Slight.) Density ...................................... 1.06 g/cm3 at 25°C (77°F) Flash Point...
http://www.chemcas.com/msds_archive/part2/cas/gm_msds/1448-92_busan_1024_6_2_2006_2_50_04_pm.asp | | | | MSDS PAGE: CAS 108-95-2 50-00-0 MSDS 03781000.asp
50-00-0 File Name : 03781000.asp LEMBARAN DATA KESELAMATAN RIBETAK® R7515P 1. PENGENALAN ZAT/SEDIAAN DAN SYARIKAT/USAHAAN Nama Produk : RIBETAK® R7515P Nama Kimia : RESIN TERMOPLASTIK FENOLIK Nombor : 7 Penggunaan Produk Resin untuk industri getah : Pengilang/Pembekal : SI Group-Ribécourt S.A.S 1111 Avenue G. Washington Bethune-Cedex 62404 Pencipta : HGW Nombor Telefon Kecemasan : Kecemasan : ORFILA: 01 45 42 59 59X` Nombor Telefon Am : Am : 0033/3/21686767 FAKS : 0033/3/21686768 2. KOMPOSISI/MAKLUMAT TENTANG RAMUAN Nama ramuan Kepekatan # CAS EINECS # R - Frasa Simbol FENOL 1% 108-95-2 203-632-7 R23/24/25, R34, T - Toksik, C - R48/20/21/22, R68 Mengakis FORMALDEHID 0.01 % 50-00-0 200-001-8 R23/24/25, R34, T - Toksik R40, R43 3. PENGENALAN BAHAYA Bahaya Tidak diklasifikasi sebagai berbahaya seperti dimaksudkan dalam peraturan pengangkutan. Kerengsaan yang sedikit Guna sejajar dengan kebersihan industri dan amalan keselamatan yang baik. 4. LANGKAH PERTOLONGAN CEMAS Kulit Mungkin kemerahan dan kerengsaan Boleh menyebabkan kesan sistemik Gunakan resin menanggal krin bersih kulit. Bilas dengan sabun dan air yang banyak. Jangan guna pelarut bersih kulit. Jika seorang merasa kurang sihat atau kelihatan gejala kerengsaan kulit, jumpa doktor. Mata Boleh menyebabkan kerengsaan Bila bersentuh dengan mata, bilas serta merta dengan air yang banyak. Dapatkan nasihat perubatan Tersedut Boleh menyebabkan kerengsaan Pindah ke udara bersih. Jika berlaku kemalangan atau merasa kurang sihat, dapatkan nasihat perubatan serta merta. Produk : RIBETAK® R7515P SDS MALAYSIA 1/ 6 LEMBARAN DATA KESELAMATAN RIBETAK® R7515P Termakan Jangan paksa muntah. Jika sedar, minum air yang banyak. Jika berlaku kemalangan atau merasa kurang sihat, dapatkan nasihat perubatan serta merta. Nasihat umum CATATAN KEPADA DOKTOR: Berikan rawatan gejala. Lihat bahagian 11 - Maklumat toksikologi 5. LANGKAH MEMADAM KEBAKARAN Media pemadam Guna zat kimia kering, CO2, semburan air atau buih "alkohol" Jangan guna pancutan air menumpu kerana ia mungkin membuat api memencar dan merebak. Penghuraian Wasap toksik mungkin terjadi. Produk penghuraian mungkin termasuk karbon oksida. Alat Pemadam Kebakaran/Arahan Suhu swapencucuhan -- data tidak terdapat Tidak mudah menyala -- mungkin menyokong pembakaran. Habuk boleh membentuk campuran mudah meledak dalam udara. Guna sejajar dengan kebersihan industri dan amalan keselamatan yang baik. Mengikuti berkenaan garispanduan, seperti National Fire Protection Association [NFPA] 654, "Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids". Wap adalah lebih berat dari udara dan mungkin merebak di paras lantai. Pemancaran berbalik boleh berlaku pada jarak yang jauh. Pakai alat pernafasan tersedia-udara bertekanan-positif dan baju perlindungan penuh daripada kimia. 6. LANGKAH-LANGKAH PEMBEBASAN SECARA TIDAK SENGAJA Langkah berjaga-jaga Alam Sekitar Elakkan kejadian habuk. Pihak berkuasa tempatan harus diberitahu jika tumpahan besar tidak boleh dibendung. Langkah waspada peribadi Pakai pakaian pelindung -- lihat bahagian 8 Gunakan peralatan tidak bunga api. Kaedah Pembersihan Buang semua sumber pencucuhan. Mengandungi tumpahan -- sebarang cara mungkin Sapukan dan sodok ke dalam bekas yang sesuai untuk dilupuskan. Simpan di tempat selamat. Jika boleh pilih kitar semula dari melupus atau membakar. 7. PENANGANAN & PENYIMPANAN Presedur penanganan Guna sejajar dengan kebersihan industri dan amalan keselamatan yang baik. Jika formasi habuk didapati, ekuipmen mesti dipadam suis, dicuci dan diservis. Untuk mengelak pencucuhan wap oleh pembebasan elektrik statik, semua bahagian peralatan dari logam mesti dibumikan. Mengikat dan bumi, sebagaimana patut. Untuk maklumat tambahan, merujuk berkenaan garispanduan, seperti National Fire Protection Association [NFPA] 77, "Recommended Practices on Static Electricity". Minimum Pencucuhan Tenaga untuk resin fenolik boleh sebagai berat sebagai 3 mJ [mi...
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50-00-0 File Name : 03782500.asp Norme de Tehnica şi Securitatea Muncii RIBETAK® XR14277A 1. IDENTIFICAREA SUBSTANŢEI / PREPARĂRII ŞI A SOCIETĂŢII / INTREPRINDERII Denumirea produsului RIBETAK® XR14277A : Denumire chimică : EMULSIE DE RĂŞINĂ FENOLIC Număr de revizuirii : 8 Utilizare produsului : Adevizi Producător / Furnizor : SI Group-Ribécourt S.A.S 1111 Avenue G. Washington Bethune-Cedex 62404 Autor : HGW Număr de telefon în caz de urgenţă ORFILA: 01 45 42 59 59X` Urgenţă Număr de telefon Generale 0033/3/21686767 Fax 0033/3/21686768 2. COMPOZIŢIA/INFORMAŢII DESPRE COMPONENTE Denumire componente Concentraţia Nr. CAS EINECS # R-Frază(e) Simbol(uri) PARA-terţiar-BUTILFENOL 1% 98-54-4 202-679-0 R36/37/38, Xi - Iritant, N - R51/53 Periculos pentru mediu FORMALDEHIDĂ 0.01 % 50-00-0 200-001-8 R23/24/25, R34, T - Toxic R40, R43 3. IDENTIFICAREA RISCURILOR Riscuri Nu este clasificat ca fiind periculos în sensul reglementărilor de transport. Iritant blând Poate provoca sensibilizarea prin inhalare şi prin contact cu ielea. Norme de igienă industriale generale. 4. MĂSURI DE PRIM AJUTOR Piele Poate roşeaţă şi iritaţie. Poate efecte sistemică. Se va folosi de răşini îndepărtarea cremă de curăţire pielea, sau se va spăla imediat cu multă apă. Nu se folosire solvenţi de curăţat pielea. Dacă iritaţia persista, consulta un medic. Ochii Poate iritaţia. În caz de contact cu ochii, se vor clăti imediat cu multă apă. Consulta un medic. Inhalare Poate Iritaţia. Muta pacient la aer curat. Dacă iritaţia persista, consulta un medic. SDS RUMANIA Produs : RIBETAK® XR14277A 1/ 7 Norme de Tehnica şi Securitatea Muncii RIBETAK® XR14277A Ingerare Nu se va induce vomă. Dacă victima este conştientă va bea multă apă. Îm timpul în îndoială sau simptome persista, consulta un medic. Indicaţii generale Indicaţii pentru medici: Conduce simptome. Vezi de asemenea secţiunea 11 -- Informaţii Toxicologice 5. NORME PCI Produse pentru stingerea incendiului În caz de incendiu, se va folosi apă pulverizată, spumă sau produs chimic uscat. Nu se folosire jet de apă puternic Descompunere Fum toxic poate fi format. Produşi de descompunere pot include oxizi de carbon. Echipamant de împotriva incendiilor / Instrucţiuni Temperatură de autoaprindere - necunoscut. Neinflamabil dar suportă combustie. Vaporii poate fi mai greu decât aerul şi poate călători înainte pământ distant surse de aprindere şi privire retrospectivă. Se vor purta combinezon de protecţie completă contra substanţelor chimice şi aparat respirator autonom. 6. MĂSURI ÎN CAZ DE ÎMPRĂŞTIERE ACCIDENTALĂ Măsuri de prevedere pentru mediu Autorităţile locale trebuie să fir avertizate dacă scurgeri semnificative nu pot fi limitate. Măsuri de prevedere individuale Se va purta îmbrăcăminte de protecţie corespunzătoare menţionate la articolul 8. Metode de curăţire Deconectare toţi surse de aprindere. Conţine scurgeri prin orice posibil. Se va mătura sau se va introduce folosind un făraş în containere adecvate pentru a fi eliminat. Recupera produsul unde posibil. 7. MANIPULARE ŞI DEPOZITARE Procedeu de manipulare Obişnuit măsuri de prevedere pentru manipulare substanţe chimice trebuie cerceta. Material pot acumula sarcini electrostatice În timpul operaţiilor de manipulare. Pentru a evita aprinderea praf datorită descărcărilor electrice statice, toate părţile metalice ale echipamentului trebuie să prezinte împământare. De informaţii suplimentare, consulta aplicabil conducere cum ar fi National Fire Protection Association [NFPA] 77, "Recommended Practices on Static Electricity". Procedeu de depozitare Se va păstra produsul într-un loc uscat şi rece. Nu se va îngheţa. 8. CONTROLUL EXPUNERII / PROTECŢIA PERSONALULUI SDS RUMANIA Produs : RIBETAK® XR14277A 2/ 7 Norme de Tehnica şi Securitatea Muncii RIBETAK® XR14277A AEL/REL [Acceptabil/Recomandată limite expunerea] FORMALDEHIDĂ 50-00-0 REL: TWA = 0.3 ppm; STEL = 0.6 ppm [Rohm & Haas] Elveţia - Limite expunerea profesională - MAKs FORMALDEHIDĂ 50-00-0 0.3 ppm MAK; 0.37 mg/m3 ...
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50-00-0 File Name : 03783000.asp FISA TEHNICA DE SECURITATE RIBAMID® C3240 1. IDENTIFICAREA SUBSTANŢEI/PREPARATULUI CHIMIC PERICULOS ŞI A SOCIETATII/INTREPRINDERII Denumirea produsului RIBAMID® C3240 : Denumire chimică : RĂŞINĂ FENOLIC BAZEAZĂ PE MELAMINĂ & FORMALDEHIDĂ Număr de revizuirii : 11 Utilizare produsului : Saturat răşini Producător / Furnizor : SI Group-Ribécourt S.A.S 1111 Avenue G. Washington Bethune-Cedex 62404 Completat de catre : HGW Adresa electronică (e-mail): sds.info@siigroup.com Număr de telefon în caz de urgenţă : Urgenţă : ORFILA: 01 45 42 59 59X` Număr de telefon : Generalităţi : 0033/3/21686767 Fax : 0033/3/21686768 2. IDENTIFICAREA PERICOLELOR Simbol(uri) Xn - Nociv Riscuri specifice Nu este clasificat ca periculos in timpul transportului. Iritant usor Poate provoca sensibilizare prin inhalare şi în contact cu pielea. Conţine componente cancerigene. Se vor folosi normele obisnuite de igiena personala. 3. COMPOZITIA/INFORMAŢII DESPRE COMPONENTE Denumire componente Concentraţie Nr. CAS EINECS # R-Frază(e) Simbol(uri) (Ch 50-00-0 l i Formaldehidă 3% 200-001-8 R23/24/25, R34, T - Toxic R40, R43 4. MĂSURI DE PRIM AJUTOR Contactul cu pielea Poate apare roşeaţă si iritarea zonelor afectate. Poate provoca efecte sistemice. Folositi o crema care sa curete pielea sau spalati cu sapun si apă din abundenta Nu folositi solventi pentru curatarea pielii. Consulati medicul daca iritatia persista. Produs : RIBAMID® C3240 SDS EU 1/ 6 FISA TEHNICA DE SECURITATE RIBAMID® C3240 Contact cu ochii Poate provoca iritatii. Dacă produsul a atins ochii, spalati imediat cu multă apă. Consultati un medic specialist. Inhalare Poate provoca iritatie Scoateti victima la aer curat. Consultati in medic dacă iritaţia persista. Ingerare Nu provocati vomă. Dati victimei sa bea multă apă. Dacă exista dubii sau daca simptomele persista, consultati medicul. Indicaţii generale In atentia medicului: Continuati sa supravegheati si sa ajutati victima, in functie de starea acesteia. Vezi de asemenea secţiunea 11 -- Informaţii Toxicologice 5. NORME PCI Produse recomandate pentru stingerea incendiului In caz de incendiu utilizati apa, spuma sau un agent uscat. Nu folositi vapori. Descompunere Poate apare fum toxic. Produsele de descompunere pot include si oxid de carbon. Echipamente/Instrucţiuni pentru stingerea incendiilor Temperatură de autoaprindere - necunoscuta. Neinflamabil, dar suportă combustie. Concentratiile mari de praf pot forma un amestec exploziv cu aerul. Asigurati un sistem de curatare, conform recomandarilor din National Fire Protection Association (NFPA) 654, ref. "Prevenirea focului si exploziei de praf provenind de la fabricarea, procesarea si manipularea particulelor solide combustibile". Vaporii pot fi mai grei decat aerul si se pot propaga la sol pina la surse de aprindere indepartate, generand reaprinderea flamei. Se va purta echipament de protecţie chimica si Aparat respirator cu presiune-pozitiva. 6. MĂSURI IMPOTRIVA PIERDERILOR ACCIDENTALE Măsuri de prevedere pentru mediu Dacă contaminarea canalizarii sau a cursurilor de apa este inevitabila, informati imediat autorităţile competente. Măsuri de prevedere individuale Purtati echipamenult de protecţie mentionat la Art. 8. Metode de curăţire Deconectati toate sursele de aprindere. Recuperati produsul imprastiat, prin toate mijloacele posibile. Măturati sau adunati produsul imprastiat si depuneti-l intr-un loc sigur. Acoperiti produsul daca este posibil. Produs : RIBAMID® C3240 SDS EU 2/ 6 FISA TEHNICA DE SECURITATE RIBAMID® C3240 7. MANIPULARE ŞI DEPOZITARE Manipulare Precautiile obisnuite pentru manipularea produselor chimice trebuie respectate. Produsul poate acumula sarcini electrostatice in timpul manipularii. Se impune asezarea pe pamant in conditii adecvate. Pentru orice recomandari suplimentare, consultati Ghidul National Fire Protection Association (NFPA) 77 "Practici recomandate pentru electricitatea statica". Minim Aprindere Energie pentru cava solide ca praf s...
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50-00-0 File Name : 04002000.asp Norme de Tehnica şi Securitatea Muncii RIBETAK® R7500E 1. IDENTIFICAREA SUBSTANŢEI / PREPARĂRII ŞI A SOCIETĂŢII / INTREPRINDERII Denumirea produsului RIBETAK® R7500E : Denumire chimică : RĂŞINĂ FENOLIC BAZEAZĂ PE PARA-TERŢIAR-OCTYLFENOL Număr de revizuirii : 5 Utilizare produsului : Răşini pentru industria cauciuc. Producător / Furnizor : SI Group-Ribécourt S.A.S 1111 Avenue G. Washington Bethune-Cedex 62404 Autor : HGW Număr de telefon în caz de urgenţă ORFILA: 01 45 42 59 59X` Urgenţă Număr de telefon Generale 0033/3/21686767 Fax 0033/3/21686768 2. COMPOZIŢIA/INFORMAŢII DESPRE COMPONENTE Denumire componente Concentraţia Nr. CAS EINECS # R-Frază(e) Simbol(uri) PARA-terţiar-OCTYLFENOL 5% 140-66-9 205-426-2 R34, R50/53 C - Coroziv, N - Periculos pentru mediu FORMALDEHIDĂ 0.01 % 50-00-0 200-001-8 R23/24/25, R34, T - Toxic R40, R43 3. IDENTIFICAREA RISCURILOR Riscuri Nu este clasificat ca fiind periculos în sensul reglementărilor de transport. Iritant blând Norme de igienă industriale generale. 4. MĂSURI DE PRIM AJUTOR Piele Poate roşeaţă şi iritaţie. Poate efecte sistemică. Se va folosi de răşini îndepărtarea cremă de curăţire pielea, sau se va spăla imediat cu multă apă. Nu se folosire solvenţi de curăţat pielea. Dacă iritaţia persista, consulta un medic. Ochii Poate iritaţia. În caz de contact cu ochii, se vor clăti imediat cu multă apă. Consulta un medic. Inhalare Poate Iritaţia. Muta pacient la aer curat. Dacă iritaţia persista, consulta un medic. SDS RUMANIA Produs : RIBETAK® R7500E 1/ 7 Norme de Tehnica şi Securitatea Muncii RIBETAK® R7500E Ingerare Nu se va induce vomă. Dacă victima este conştientă va bea multă apă. Îm timpul în îndoială sau simptome persista, consulta un medic. Indicaţii generale Indicaţii pentru medici: Conduce simptome. Vezi de asemenea secţiunea 11 -- Informaţii Toxicologice 5. NORME PCI Produse pentru stingerea incendiului În caz de incendiu, se va folosi apă pulverizată, spumă sau produs chimic uscat. Nu se folosire jet de apă puternic Descompunere Fum toxic poate fi format. Produşi de descompunere pot include oxizi de carbon. Echipamant de împotriva incendiilor / Instrucţiuni Temperatură de autoaprindere - necunoscut. Neinflamabil dar suportă combustie. Concentraţii mari de praf poate forma amestecuri aer inflamabile/explozive. Asigura bun igienă industriale generale sunt uzat şi aplicabil conducere cum ar fi National Fire Protection Association [NFPA] 654, "Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids". Vaporii poate fi mai greu decât aerul şi poate călători înainte pământ distant surse de aprindere şi privire retrospectivă. Se vor purta combinezon de protecţie completă contra substanţelor chimice şi aparat respirator autonom. 6. MĂSURI ÎN CAZ DE ÎMPRĂŞTIERE ACCIDENTALĂ Măsuri de prevedere pentru mediu Se va evita ridicare praf. Autorităţile locale trebuie să fir avertizate dacă scurgeri semnificative nu pot fi limitate. Măsuri de prevedere individuale Se va purta îmbrăcăminte de protecţie corespunzătoare menţionate la articolul 8. Se va folosi nescânteiere unealtă. Metode de curăţire Deconectare toţi surse de aprindere. Conţine scurgeri prin orice posibil. Se va mătura sau se va introduce folosind un făraş în containere adecvate pentru a fi eliminat. Recupera produsul unde posibil. 7. MANIPULARE ŞI DEPOZITARE Procedeu de manipulare Obişnuit măsuri de prevedere pentru manipulare substanţe chimice trebuie cerceta. Dacă se observă formarea de praf, echipamentul va fi oprit, curăţat şi apoi verificat. Material pot acumula sarcini electrostatice În timpul operaţiilor de manipulare. Pentru a evita aprinderea praf datorită descărcărilor electrice statice, toate părţile metalice ale echipamentului trebuie să prezinte împământare. De informaţii suplimentare, consulta aplicabil conducere cum ar fi National Fire Protection Association [NFPA] 77, "Recommended Practices on Static Electricity". Minim...
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50-00-0 File Name : 50-00-0_v3.asp MATERIAL SAFETY DATA SHEET PRODUCT NAME: IRGASOL DAM MSDS CODE : C339474 VERSION : 2 UPDATED : August 2001 Not classified as hazardous according to criteria of NOHSC Australia : =--------------------------------------------------------------------= COMPANY DETAILS =--------------------------------------------------------------------= CIBA SPECIALTY CHEMICALS 235 Settlement Road 6/8 Donaldson Street THOMASTOWN VIC 3074 NORTH WYONG NSW 2259 Phone: (03) 9282 0600 Phone: (02) 43 503 200 Fax: (03) 9465 0031 Fax: (02) 43 532 136 Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607 =--------------------------------------------------------------------= Attn: CHEMICAL SAFETY OFFICER or EMERGENCY RESPONSE SERVICES =--------------------------------------------------------------------= IDENTIFICATION =--------------------------------------------------------------------= PRODUCT NAME ..: IRGASOL DAM Other name(s)..: SEE "INGREDIENTS TEXT" BELOW Correct Shipping name: NOT APPLICABLE UN Number . . . . . : FREE Dangerous Goods Class Packaging and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE HAZCHEM Code . . . . : NOT APPLICABLE Poison Schedule . . : NONE ALLOCATED USE: TEXTILE CHEMICAL _________________________________ Appearance. . . . . . : BROWN GRANULAR; NO ODOUR Boiling/Melting point : NOT APPLICABLE Vapour pressure . . . : NOT APPLICABLE Density . . . . . . . : 1.0 - 1.1 (g/cc @ 20 deg.C) Flash Point . . . . . : > 100 (deg.C DIN 51758 method) Flammability Limits . : not applicable Solubility in water . : 100 (g/L @ 20 deg.C) _________________________________ Decomposition temperature: > 300 oC Ignition point : > 600 oC (DIN 51794) pH : 5.0 - 9.0 at 100 g/l in water Oxidising properties : NONE _________________________________ Chemical Entity CAS No. Proportion FORMALDEHYDE 50-00-0 0.01 % OBSERVE "EXPOSURE LIMIT" NON HAZARDOUS COMPONENTS TO 100% ANIONIC- CONDENSATION PRODUCT OF NAPHTHA LENE SULFONIC ACID, SODIUM SALT. =--------------------------------------------------------------------= =--------------------------------------------------------------------= HEALTH HAZARD INFORMATION =--------------------------------------------------------------------= _________________________________ Swallowed : SLIGHT (Oral,Rat LD50) > 5000 mg/kg Eye . . . : NON-IRRITANT - EC 83 RABBIT, REFER TO "HEALTH EFFECTS CHRONIC" BELOW Skin . . : NON-IRRITANT - EC 83 RABBIT, REFER TO "HEALTH EFFECTS- CHRONIC" BELOW. Inhaled . : NOT YET AVAILABLE - REFER TO "HEALTH EFFECTS- CHRONIC" BELOW. _________________________________ THIS PRODUCT CONTAINS FORMALDEHYDE, WHICH IS CLASSIFIED BY WORKSAFE AUSTRALIA AS A CATEGORY 2 CARCINOGEN. THIS IS HIGHLY IRRITATING TO THE EYES, SKIN AND MUCUS MEMBRANES. IT IS KNOWN TO CAUSE NASAL TUMOURS IN RATS AND CAN BE REGARDED AS CAUSING IRREVERSIBLE EFFECTS TO HUMANS ON REPEATED OVEREXPOSURE. CAN CAUSE DERMITITIS. WHEN USING THIS PRODUCT, AIR MONITORING SHOULD BE CONDUCTED TO ENSURE COMPLIANCE WITH TLV'S. MONITORING CAN BE ARRANGED BY CIBA-GEIGY AUSTRALIA LIMITED. _________________________________ Swallowed : WASH OUT MOUTH WITH WATER. DRINK PLENTY OF WATER. SEEK MEDICAL ADVICE. Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER FOR AT LEAST 15 MINUTES. Skin . . : CLEAN CONTAMINATED AREAS WITH SOAP AND PLENTY OF RUNNING WATER. REMOVE CONTAMINATED CLOTHING. Inhaled . : REMOVE PATIENT TO FRESH AIR, REST. SEEK MEDICAL ATTENTION IF YOU FEEL UNWELL OR IF EXPOSURE PROLONGED. Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN. =--------------------------------------------------------------------= PRECAUTIONS FOR USE =--------------------------------------------------------------------= _________________________________ TLV : (WORKSAFE) FORMALDEHYDE 1ppm STEL : (WORKSAFE) FORMALDEHYDE 2ppm AVOID EXCEEDING EXPOSURE LIMITS BY USE OF VENTILATION AND/OR PERSONAL PROTECTION FOLLOW GOOD WORKING PRACTICE : HANDLE WITH CARE, AVOID INGESTION, INHALATION, EYE OR SKIN CONTA...
http://www.chemcas.org/msds_archive/msds_01/cas/ga_msds/50-00-0_v3.asp | | | | MSDS CAS# 50-00-0 50-00-0.asp
50-00-0 File Name : 50-00-0.asp SICHERHEITSDATENBLATT RIBAMID® C4221 1. STOFF-/ZUBEREITUNGS- UND FIRMENBEZEICHNUNG Produktname : RIBAMID® C4221 Chemische HARNSTOFF-MELAMIN-FORMALDEHYDHARZ LÖSUNG Bezeichnung : Revisions-Nr : 13 Produktverwendung : Harz für Papier. Hersteller/Lieferant : SI Group-Ribécourt S.A.S 1111 Avenue G. Washington Bethune-Cedex 62404 Vervollständigt : HGW Email Adresse: sds.info@siigroup.com Notrufnummer : Notrufnummer : ORFILA: 01 45 42 59 59X` Telefon : Allgemeines : 0033/3/21686767 Telefax : 0033/3/21686768 2. MÖGLICHE GEFAHREN Symbol(e) Xn - Gesundheitsschädlich Besondere Gefahren Nicht als Gefahrstoff eingestuft. Sensibilisierung durch Einatmen und Hautkontakt möglich. Enthält krebsartige Bestandteile. Gute Hygiene- und Körperpflegepraktiken befolgen 3. ZUSAMMENSETZUNG/ANGABEN ZU BESTANDTEILEN Inhaltsstoffe Konzentration CAS-Nr. EINECS-Nr. Gefahrenhinweise Symbol(e) FORMALDEHYD 5% 50-00-0 200-001-8 R23/24/25, R34, T - Giftig R40, R43 4. ERSTE-HILFE-MASSNAHMEN Hautkontakt Möglicherweise tritt Rötung und Reizung in den betroffenen Bereichen auf Kann systemische Auswirkungen verursachen Die Haut mit einer harzentfernenden Creme reinigen, oder mit reichlich und Wasser und Seife waschen. Die Haut nicht mit Lösungsmitteln reinigen Ärztlich behandeln lassen, falls die Reizung andauert Augenkontakt Kann Reizungen verursachen Falls die Substanz in die Augen gelangt ist, mit reichlich Wasser auswaschen Ärztlichen Rat einholen Produkt : RIBAMID® C4221 SDS EU 1/ 6 SICHERHEITSDATENBLATT RIBAMID® C4221 Einatmen Kann Reizungen verursachen Den Patienten an die frische Luft bringen Ärztlich behandeln lassen, falls die Reizung andauert Verschlucken Nicht zum Erbrechen bringen Reichlich Wasser zu trinken geben Im Zweifelsfall oder wenn sich die Symptome nicht bessern, Arzt aufsuchen Allgemeine Hinweise HINWEIS FÜR ÄRZTE: Beobachtung und gemäß dem Zustand des Patienten unterstützend behandeln. Siehe Teil 11 - Toxikologische Information 5. MASSNAHMEN ZUR BRANDBEKÄMPFUNG Geeignete Löschmittel Zum Löschen Wasser, Schaum oder Pulver verwenden. Keinen Wasservollstrahl verwenden Thermische Zersetzung Toxischer Rauch kann entstehen Zersetzungsprodukte können Kohlenoxyde enthalten. Brandbekämfungsausrüstung / Anweisungen Selbstentzündungspunkt - nicht bekannt Nicht entflammbar, unterstützt jedoch die Verbrennung Dämpfe können schwerer als Luft sein und sich in Bodennähe ausbreiten, zu einer entfernten Zündquelle gelangen und sich entzünden. Chemikalienbeständige Schutzkleidung und Überdruck-Atemgerät tragen. 6. MASSNAHMEN BEI UNBEABSICHTIGTER FREISETZUNG Umweltschutzmaßnahmen Ist eine Verunreinigung von Abwassersystemen oder Wasserläufen unvermeidlich, sofort entsprechende Behörden informieren Personenbezogene Vorsichtsmaßnahmen Schutzkleidung gemäss Abschnitt 8 tragen Verfahren zur Reinigung/Aufnahme Alle Zündquellen ausschalten Die weitere Freisetzung unbedingt stoppen. Verschüttetes Material aufwischen oder aufschaufeln und an einen sicheren Ort bringen Produkt nach Möglichkeit wieder aufnehmen 7. HANDHABUNG UND LAGERUNG Handhabung Die allgemeinen Vorsichtsmassnahmen beim Umgang mit Chemikalien sind zu beachten Das Material kann sich beim Umgang statisch aufladen. Verbindungen und Erdung müssen angemessen sein. Für zusätzliche Empfehlungen konsultieren Sie bitte die entsprechenden Richtlinien im National Fire Protection Association [NFPA] 77, “Recommended Practices on Static Electricity". Lagerung An einem kühlen, trockenen Ort aufbewahren Nicht einfrieren. 8. EXPOSITIONSBEGRENZUNG UND PERSÖNLICHE SCHUTZMAßNAHMEN Produkt : RIBAMID® C4221 SDS EU 2/ 6 SICHERHEITSDATENBLATT RIBAMID® C4221 AEL/REL [Arbeitsplatzgrenzwert] FORMALDEHYD 50-00-0 REL: TWA = 0.3 ppm; STEL = 0.6 ppm [Rohm & Haas] Deutschland - DFG - Arbeitsplatzgrenzwert - Obergrenze FORMALDEHYD 50-00-0 0.6 ppm Spitzenbegrenzung; 0.74 mg/m3 m3 Spitzenbegrenzung (während dem Umgang mit den Zubreitungen soll sichergestellt werden, daß keine Reizeffekte auftreten) Deut...
http://www.chemcas.org/msds_archive/msds_01/cas/gb_msds/50-00-0.asp | | | | MSDS CAS# 50-00-0 50-00-0_v1.asp
50-00-0 File Name : 50-00-0_v1.asp Material Safety Data Sheet SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Phenol-Formaldehyde Bonded Wood Products plus a polyurethane film: softwood plywood (veneer core), laminated veneer lumber, and wood I- joists. Trade Name: Laminated veneer lumber (LVL): Versa-Lam®, Versa-Rim®, Plywood: Sheathing Wood I-Joist: BCI® Manufacturer/Distributor: Boise Cascade, LLC P.O. Box 62 Boise, ID 83707-0062 Phone Number: 1/800/228-0815 Description: The plywood panel product contains bonded layers of softwood veneer. The laminated veneer lumber is manufactured with all grain parallel with the length of the member. The wood I-joists are manufactured with LVL flanges bonded to either plywood or OSB webs. These products are bonded together with resins that comply with ASTM D2559. SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS C.A.S. # PERCENT MATERIAL OR COMPONENT Formaldehyde 50-00-0 0.1% by weight Solid Polyurethane Film Not Applicable 2.67% by weight Wood Dust (soft and most hardwoods, except Western Red Not Applicable Cedar, Beech, and Oak) Component OSHA PEL ACGIH TLV Formaldehyde 0.75 ppm TWA 0.3 ppm ceiling (0.1% by weight) 2.0 ppm STEL 0.5 ppm Action Level Solid Polyurethane Film Not applicable Not applicable 3 Nonallergenic and Wood Dust 15.0 mg/m TWA (Total) noncarcinogenic 2 mg/m3 3 5.0 mg/m TWA Western Red Cedar 0.5 mg/m3 (Respirable) Other respiratory allergenic wood dust, Birch, Mahogan, Teak, Walnut, Oak and Beech 1 mg/m3 SECTION 3 HAZARDS IDENTIFICATION INHALATION Dust may cause nasal dryness, irritation, coughing, and sinusitis. 3 Repeated exposures (even below 5 mg/m ) to certain wood dusts can produce allergic responses in some sensitive individuals. SKIN CONTACT Both formaldehyde and various species of wood dust may evoke allergic contact dermatitis in sensitized individuals. SKIN ABSORPTION Not applicable for product in purchased form. EYE CONTACT Dust may cause temporary irritation, mechanical irritation, or a burning sensation to the eyes. INGESTION Not applicable for product in purchased form. WOOD DUST: Wood dust may cause nasal dryness, irritation, and obstruction. Coughing, wheezing, and sneezing; sinusitis and prolonged colds have also been reported. Depending on species, may cause respiratory sensitization and/or irritation. Wood dust is not classified as a potential cancer hazard by OSHA. The National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) do classify wood dust as a carcinogen to humans (Group 1). This classification is based primarily on IARC’s evaluation of increased risk in the occurrence of adenocarcinomas of the nasal cavities and paranasal sinuses associated with exposure to wood dust. IARC did not find sufficient evidence to associate cancers of the oropharynx, hypopharynx, lung, lymphatic and hematopoietic systems, stomach, colon, or rectum with exposure to wood dust. FORMALDEHYDE: May cause temporary irritation to eyes, nose and throat. Some reports suggest that formaldehyde may cause respiratory sensitization, such as asthma, and the preexisting respiratory disorders may be aggravated by exposure. Formaldehyde is listed by IARC as a probable human carcinogen. The NTP includes formaldehyde in the Annual Report on Carcinogens. Formaldehyde is regulated by OSHA as a potential cancer agent. In studies involving rats, formaldehyde has been shown to cause nasal cancer after long-term exposure to very high concentrations (14+ ppm), far above those normally found in the workplace using this product. The National Cancer Institute (NCI) conducted an epidemiological study of industrial workers exposed to formaldehyde (published June 1986). The NCI concluded that the data provides little evidence that mortality from cancer is associated with formaldehyde exposure at the levels experienced by workers in the study. Polyurethane Film is not listed as a carcinogen by the International Agency for Research on Cancer, t...
http://www.chemcas.org/msds_archive/msds_01/cas/gb_msds/50-00-0_v1.asp | | | | MSDS CAS# 50-00-0 50-00-0_v2.asp
50-00-0 File Name : 50-00-0_v2.asp TM Material Safety Data Sheet SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Phenol-Formaldehyde Bonded Wood Products plus a polyurethane film: softwood and hardwood plywood (veneer core), oriented strand board, laminated veneer lumber, and wood I-joists. Trade Name: Laminated veneer lumber (LVL): VERSA-LAM®, VERSA- RIM®, Plywood: Sheathing Oriented Strand Board (OSB): Sheathing Wood I-Joist: BCI® Manufacturer/Distributor: Boise Cascade Corporation P.O. Box 62 Boise, ID 83707-0062 Phone Number: 208/384-6534 Description: The plywood panel product contains bonded layers of softwood and hardwood veneer. The Oriented Strand Board is manufactured with narrow strands of wood fiber connected lengthwise and crosswise in layers. The laminated veneer lumber is manufactured with all grain parallel with the length of the member. The wood I-joists are manufactured with LVL flanges bonded to either plywood or OSB webs. These products are bonded together with resins that comply with ASTM D2559. SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS C.A.S. # PERCENT MATERIAL OR COMPONENT Formaldehyde 50-00-0 0.1% by weight Solid Polyurethane Film Not Applicable 2.67% by weight Wood Dust (soft and most hardwoods, except Western Not Applicable Red Cedar, Beech, and Oak) Component OSHA PEL ACGIH TLV Formaldehyde 0.75 ppm TWA 0.3 ppm STEL (0.1% by weight) 2.0 ppm STEL 0.5 ppm Action Level Solid Polyurethane Film Not applicable Not applicable 3 Wood Dust (soft and most 15.0 mg/m TWA Wood Dust hardwoods, except Western (Total) -Nonallergenic & 3 Red Cedar, Beech, and Oak) 5.0 mg/m TWA noncarcinogenic - 2 mg/m3 (Respirable) -other respiratory allergenic wood dust - 1 mg/m3 MSDS - LVL SECTION 3 HAZARDS IDENTIFICATION INHALATION Dust may cause nasal dryness, irritation, coughing, and sinusitis. Repeated 3 exposures (even below 5 mg/m ) to certain wood dusts can produce allergic responses in some sensitive individuals. SKIN CONTACT Both formaldehyde and various species of wood dust may evoke allergic contact dermatitis in sensitized individuals. SKIN ABSORPTION Not applicable for product in purchased form. EYE CONTACT Dust may cause temporary irritation, mechanical irritation, or a burning sensation to the eyes. INGESTION Not applicable for product in purchased form. WOOD DUST: Wood dust may cause nasal dryness, irritation, and obstruction. Coughing, wheezing, and sneezing; sinusitis and prolonged colds have also been reported. Depending on species, may cause respiratory sensitization and/or irritation. Wood dust is not considered a potential cancer hazard by OSHA. The National Toxicology Program (NTP) and the International Agency for Research on Cancer (IARC) classifies wood dust as a carcinogen to humans (Group 1). This classification is based primarily on IARC’s evaluation of increased risk in the occurrence of adenocarcinomas of the nasal cavities and paranasal sinuses associated with exposure to wood dust. IARC did not find sufficient evidence to associate cancers of the oropharynx, hypopharynx, lung, lymphatic and hematopoietic systems, stomach, colon, or rectum with exposure to wood dust. FORMALDEHYDE: May cause temporary irritation to eyes, nose and throat. Some reports suggest that formaldehyde may cause respiratory sensitization, such as asthma, and the preexisting respiratory disorders may be aggravated by exposure. Formaldehyde is listed by IARC as a probable human carcinogen. The NTP includes formaldehyde in the Annual Report on Carcinogens. Formaldehyde is regulated by OSHA as a potential cancer agent. In studies involving rats, formaldehyde has been shown to cause nasal cancer after long-term exposure to very high concentrations (14+ ppm), far above those normally found in the workplace using this product. The National Cancer Institute (NCI) conducted an epidemiological study of industrial workers exposed to formaldehyde (published June 1986). The NCI concluded that the data provides l...
http://www.chemcas.org/msds_archive/msds_01/cas/gb_msds/50-00-0_v2.asp | | | | MSDS CAS# 50-00-0 50-00-0_v4.asp
50-00-0 File Name : 50-00-0_v4.asp Page 1 of 7 Material 24 Hour Emergency Phone Numbers: Medical: 1-800-327-3874 1-513-558-5111 Safety Transportation: 1-800-535-5053 1-352-323-3500 Data Sheet NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Weldwood Waterproof Resorcinol Glue (powder Revision Date: 04/21/2005 catalyst Part A) Product UPC 7079800226, 7079800227, 7079800228, Supercedes: 12/30/1999 Number: 7079800229, 7079800230, 7079800232 Product Use/Class: Resorcinol Catalyst MSDS Number: 00030222001 Manufacturer: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327-8477 (non-emergency matters) Section 2 - Composition / Information On Ingredients ACGIH Chemical Name CASRN WT% ACGIH TWA ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin STEL Paraformaldehyde 30525-89 -4 60-100 N.E. N.E. N.E. N.E. N.E. N.E. No Cellulose 9004 -34-6 10-30 10 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No Formaldehyde 50-00-0 3-7 N.E. N.E. 0.3 PPM 0.75 PPM 2 PPM N.E. No Exposure Notes: 50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Page 2 of 7 Section 3 - Hazards Identification Emergency Overview: A tan powder with a slight formaldehyde odor. WARNING! Harmful if swallowed or absorbed through the skin. May cause allergic skin reaction. Causes skin irritation. Causes chemical burns to eyes. May cause allergic respiratory reaction. Harmful if inhaled. Will polymerize at high temperatures with some evolution of heat. Combustible dust when finely divided or suspended in air. Flammable solid. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Causes eye burns. Effects Of Overexposure - Skin Contact: Causes skin irritation. Harmful if absorbed through the skin. Repeated skin contact may produce an allergic sensitization. In such cases, incidental (minor) contact may cause allergic rashes. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Effects Of Overexposure - Ingestion: May result in irritation or burns to the mouth and digestive system. Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage. Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic to humans by inhalation. The Intern...
http://www.chemcas.org/msds_archive/msds_01/cas/gb_msds/50-00-0_v4.asp | | | | MSDS Paraformaldehyde CAS 50-00-0 MSDS
50-00-0 SYNONYMS : Section 1 - Chemical Product and Company Identification MSDS Name: Paraformaldehyde Catalog Numbers: AC169650000, AC169650010, AC169650025, AC169650250, AC416780000, AC416780010, AC416780030, AC416780250, AC416785000, NC9920507, NC9953590, O4042-500, PARAFORM, S70102, S80114, T353-500 Synonyms: Polyformaldehyde; Polyoxymethylene; Formaldehyde polymer; Polyoxymethylene glycol; Trioxymethylene; Paraform. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS# Chemical Name Percent EINECS/ELINCS 30525-89-4 Paraformaldehyde >90 unlisted 50-00-0 Formaldehyde off-gas 200-001-8 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: white powder. Flash Point: 70 deg C. Warning! Flammable solid. Causes eye, skin, and respiratory tract irritation. May cause allergic respiratory and skin reaction. Harmful if inhaled. May be harmful if swallowed or absorbed through the skin. Product may generate formaldehyde which can cause cancer. Target Organs: Respiratory system, eyes, skin. Potential Health Effects Eye: May result in corneal injury. Causes severe eye irritation and burns. Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with dust causes drying, cracking, and scaling of the skin. Ingestion: Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause systemic toxicity with acidosis. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. Inhalation: May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation. May cause anosmia (loss of smell). Inhalation of high concentrations may cause pulmonary edema. Formaldehyde may cause asthmatic symptoms by acting as an immunological sensitizer. Harmful if inhaled. Chronic: Prolonged or repeated eye contact may cause conjunctivitis. Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause sensitization dermatitis. Contains formaldehyde which can cause cancer in humans. There is sufficient evidence that formaldehyde causes nasopharyngeal cancer in humans, a rare cancer in developed countries. There is limited evidence that formaldehyde causes cancer of the nasal cavity and paranasal sinuses and strong but not sufficient evidence for leukemia. Section 4 - First Aid Measures Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid immediately. Skin: In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical aid if symptoms occur. Wash clothing before reuse. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Flammable solid. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Dust from this material can form explosive organic dust cloud. Extinguishing Media: Use water spray, dry chemical, "alcohol resistant" foam, or carbon d...
http://www.chemcas.org/drug/analytical/cas/50-00-0.asp | | | | MSDS Sulfuric acid solution, 0.02 N (N/50) CAS 50-00-0 MSDS
50-00-0 SYNONYMS : Section 1 - Chemical Product and Company Identification MSDS Name: Sulfuric acid solution, 0.02 N (N/50) Catalog Numbers: SA226-1, SA226-20, SA226-4 Synonyms: Sulfuric acid 0.02N. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS# Chemical Name Percent EINECS/ELINCS 7732-18-5 Water 99.906 231-791-2 7664-93-9 Sulfuric acid 0.094 231-639-5 50-00-0 Formaldehyde .005% 200-001-8 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: colorless liquid. Caution! May cause eye, skin, and respiratory tract irritation. Target Organs: Respiratory system, eyes, skin. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. Chronic: No information found. Section 4 - First Aid Measures Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid. Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Flash Point: Not applicable. Autoignition Temperature: Not applicable. Explosion Limits, Lower: Not available. Upper: Not available. NFPA Rating: (estimated) Health: 1; Flammability: 0; Instability: 0 Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Storage: Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits Chemical Name ACGIH NIOSH OSHA - Final PELs Water none listed none listed none listed Sulfuric acid 0.2 mg/m3 TWA (thoracic fraction) 1 mg/m3 TWA 15 mg/m3 IDLH 1 mg/m3 TWA Formaldehyde 0.3 ppm Ceiling 0.016 ppm TWA 20 ppm IDLH 0.75 ppm TWA; 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer ha zard - see 29 CFR 1910.1048) OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Sulfuric acid: 1 mg/m3 TWA Formaldehyde: 3 ppm TWA (unless specified in 1910.1048) Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Glove protection is not ...
http://www.chemcas.org/drug/analytical/cas/50-00-0_v1.asp |
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| ALL PAGES On Chemical Properties IN THIS GROUP
| | Name | CAS | Synonyms | Molecular Formula | Molecular Weight |
| 3-O-Ethylascorbic acid |
86404-04-8
| (5R)-5-[(1S)-1,2-dihydroxyethyl]-4-ethoxy-3-hydroxyfuran-2(5H)-one | C8H12O6 | 204.063 |
| Ethylene glycol |
107-21-1
| ethylene glycol | C2H6O2 | 62.037 |
| Ethylene glycol, cyclic sulfate |
1072-53-3
| 1,3,2-dioxathiolane 2,2-dioxide | C2H4O4S | 119.952 |
| Ethylene imine |
151-56-4
| aziridine | C2H5N | 43.042 |
| Ethylene oxide |
75-21-8
| oxirane | C2H4O | 44.026 |
| Ethylene urea |
120-93-4
| imidazolidin-2-one | C3H6N2O | 86.048 |
| Ethylenebisdithiocarbamate, disodium |
142-59-6
| disodium ethane-1,2-diylbis(dithiocarbamate) | C4H10N2S4Na2 | 259.952 |
| 1-Ethyleneoxy-3,4-epoxycyclohexane |
106-87-6
| 3-oxiran-2-yl-7-oxabicyclo[4.1.0]heptane | C8H12O2 | 140.084 |
| Ethylhydrazine.HCl |
18413-14-4
| ethylhydrazine hydrochloride | C2HN2Cl | 87.983 |
| Ethylnitrosocyanamide |
38434-77-4
| ethyl(nitroso)cyanamide | C3H5N3O | 99.043 |
| Ethylphenylacetylurea |
90-49-3
| N-(aminocarbonyl)-2-phenylbutanamide | C11H14N2O2 | 206.106 |
| 4-Ethylsulphonylnaphthalene-1-sulfonamide |
842-00-2
| 4-(ethylsulfonyl)naphthalene-1-sulfonamide | C12H13NO4S2 | 290.966 |
| Ethynodiol diacetate |
297-76-7
| (3beta,17beta)-17-ethynylestr-4-ene-3,17-diyl diacetate | C24H32O4 | 384.23 |
| Etodolac |
41340-25-4
| [1,8-diethyl-1,3,4,9-tetrahydropyrano[3,4-b]indol-1-yl]acetic acid | C17H21NO3 | 287.152 |
| Fadrozole.HCl |
102676-31-3
| 4-(5,6,7,8-tetrahydroimidazo[1,5-a]pyridin-5-yl)benzonitrile hydrochloride | C14H14N3Cl | 259.088 |
| Fenaminosulf, formulated |
140-56-7
| [4-(dimethylamino)phenyl]diazenesulfonic acid | C8H11N3O3S | 225.021 |
| Ferric chloride |
7705-08-0
| iron(3+) trichloride | Cl3Fe | 160.841 |
| Ferric citrate tetrahydrate |
2338-05-8
| | C6H8O11Fe | 311.942 |
| Ferric dimethyldithiocarbamate |
14484-64-1
| iron(3+) tris(dimethyldithiocarbamate) | C9H18N3S6Fe | 415.917 |
| Finasteride |
98319-26-7
| (4aR,4bS,6aS,7S,9aS,9bS,11aR)-N-(tert-butyl)-4a,6a-dimethyl-2-oxo-2,4a,4b,5,6,6a,7,8,9,9a,9b,10,11,11a-tetradecahydro-1H-indeno[5,4-f]quinoline-7-carboxamide | C23H36N2O2 | 372.278 |
| Flecainide acetate |
54143-56-5
| N-[piperidin-2-ylmethyl]-2,5-bis(2,2,2-trifluoroethoxy)benzamide acetate | C19H24N2O5F6 | 474.159 |
| Fluconazole |
86386-73-4
| 2-(2,4-difluorophenyl)-1,3-di-1H-1,2,4-triazol-1-ylpropan-2-ol | C13H12N6OF2 | 306.104 |
| Fluometuron |
2164-17-2
| N,N-dimethyl-N'-[3-(trifluoromethyl)phenyl]urea | C10H11N2OF3 | 232.082 |
| N-(2-Fluorenyl)-2,2,2-trifluoroacetamide |
363-17-7
| N-9H-fluoren-2-yl-2,2,2-trifluoroacetamide | C15H10NOF3 | 277.071 |
| Fluoride, sodium |
7681-49-4
| sodium fluoride | H2FNa | 44.004 |
| 4'-Fluoro-4-aminodiphenyl |
324-93-6
| 4'-fluorobiphenyl-4-amine | C12H10NF | 187.08 |
| N-4-(4'-Fluorobiphenyl)acetamide |
398-32-3
| N-(4'-fluorobiphenyl-4-yl)acetamide | C14H12NOF | 229.09 |
| 2-Fluoroethyl-nitrosourea |
69112-98-7
| N-(2-fluoroethyl)-N-nitrosourea | C3H6N3O2F | 135.044 |
| 5-Fluorouracil |
51-21-8
| 5-fluoropyrimidine-2,4(1H,3H)-dione | C4H3N2O2F | 130.018 |
| Fluoxetine.HCl |
59333-67-4
| N-methyl-3-phenyl-3-[4-(trifluoromethyl)phenoxy]propan-1-amine hydrochloride | C17HNOClF3 | 326.97 |
| Fluvastatin |
93957-54-1
| (3R,5S,6E)-7-[3-(4-fluorophenyl)-1-isopropyl-1H-indol-2-yl]-3,5-dihydroxyhept-6-enoic acid | C24H26NO4F | 411.184 |
| Formaldehyde |
50-00-0
| formaldehyde | CH2O | 30.011 |
| Formic acid 2-[4-(2-furyl)-2-thiazolyl] hydrazide |
31873-81-1
| N'-[4-(2-furyl)-1,3-thiazol-2-yl]formic hydrazide | C8H7N3O2S | 209.026 |
| Formic acid 2-(4-methyl-2-thiazolyl) hydrazide |
32852-21-4
| N'-(4-methyl-1,3-thiazol-2-yl)formic hydrazide | C5H7N3OS | 157.031 |
| Formic acid 2-[4-(5-nitro-2-furyl)-2-thiazolyl]hydrazide |
3570-75-0
| N'-[4-(5-nitro-2-furyl)-1,3-thiazol-2-yl]formic hydrazide | C8H6N4O4S | 254.011 |
| 1-Formyl-3-thiosemicarbazide |
2302-84-3
| 2-formylhydrazinecarbothioamide | C2H5N3OS | 119.015 |
| Formylhydrazine |
624-84-0
| formic hydrazide | CH4N2O | 60.032 |
| Fosetyl Al |
39148-24-8
| aluminum tris(ethyl phosphonate) | C6H3O9P3Al | 338.881 |
| Fumonisin B1 |
116355-83-0
| 2,2'-{(19-amino-11,16,18-trihydroxy-4,9-dimethylicosane-6,7-diyl)bis[oxy(2-oxoethane-2,1-diyl)]}disuccinic acid | C34H59NO15 | 721.388 |
| 2-Furaldehyde semicarbazone |
2411-74-7
| 2-furaldehyde semicarbazone | C6H7N3O2 | 153.054 |
| Furosemide |
54-31-9
| 5-(aminosulfonyl)-4-chloro-2-[(2-furylmethyl)amino]benzoic acid | C12H11N2O5SCl | 325.976 |
| Fusarenon-X |
23255-69-8
| (3beta,4alpha,6beta,11xi)-3,7,15-trihydroxy-8-oxo-12,13-epoxytrichothec-9-en-4-yl acetate | C17H22O8 | 354.131 |
| Gallic acid |
149-91-7
| 3,4,5-trihydroxybenzoic acid | C7H6O5 | 170.022 |
| Gemcadiol |
35449-36-6
| 2,2,9,9-tetramethyldecane-1,10-diol | C14H30O2 | 230.225 |
| Gemfibrozil |
25812-30-0
| 5-(2,5-dimethylphenoxy)-2,2-dimethylpentanoic acid | C15H22O3 | 250.157 |
| Gentian violet |
548-62-9
| N-(4-{bis[4-(dimethylamino)phenyl]methylene}cyclohexa-2,5-dien-1-ylidene)-N-methylmethanaminium | C25H30N3 | 372.244 |
| Gibberellic acid |
77-06-5
| (1R,2R,4aS,7S,9aR,10S)-2,7-dihydroxy-1-methyl-8-methylene-13-oxo-1,2,4b,5,6,7,8,9,10,10a-decahydro-4a,1-(epoxymethano)-7,9a-methanobenzo[a]azulene-10-carboxylic acid | C19H22O6 | 346.142 |
| Glu-P-1 |
67730-11-4
| 6-methylpyrido[3',2':4,5]imidazo[1,2-a]pyridin-2-amine | C11H10N4 | 198.091 |
| Glu-P-2 |
67730-10-3
| pyrido[3',2':4,5]imidazo[1,2-a]pyridin-2-amine | C10H8N4 | 184.075 |
| l-Glutamic acid |
56-86-0
| (2S)-2-aminopentanedioic acid | C5H9NO4 | 147.053 |
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