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CAS 80-62-6 Properties

MSDS  
: Methyl methacrylate
CAS  : 80-62-6
Molecular Formula  
: C5H8O2
Molecular Weight  
: 100.052
SYNONYMS  : methyl 2-methylacrylate

  
MSDS LIST:
  • MSDS Methacrylic acid, methyl ester, polymer with butylacrylate and styrene CAS 80-62-6 MSDS * Butyl acrylate copolymer with methyl methacrylate and styrene * Lakris 25T * Methyl methacrylate copolymer with butyl acrylate and styrene * Styrene copolymer with butyl acrylate and methyl methacrylate
    80-62-6 SYNONYMS   : * Butyl acrylate copolymer with methyl methacrylate and styrene * Lakris 25T * Methyl methacrylate copolymer with butyl acrylate and styrene * Styrene copolymer with butyl acrylate and methyl methacrylate *** CHEMICAL IDENTIFICATION *** RTECS NUMBER : OZ5100000 CHEMICAL NAME : Methacrylic acid, methyl ester, polymer with butyl acrylate and styrene LAST UPDATED : 199403 DATA ITEMS CITED : 1 MOLECULAR FORMULA : (C5-H8-O2.C7-H12-O2.C8-H8)x SYNONYMS/TRADE NAMES : * Butyl acrylate copolymer with methyl methacrylate and styrene * Lakris 25T * Methyl methacrylate copolymer with butyl acrylate and styrene * Styrene copolymer with butyl acrylate and methyl methacrylate *** HEALTH HAZARD DATA *** ** ACUTE TOXICITY DATA ** TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >10 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(6),86,1990 *** END OF RECORD *** ...
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  • MSDS Methacrylic acid, methyl ester CAS 80-62-6 MSDS * Acrylic acid, 2-methyl-, methyl ester * Metakrylan metylu * Methacrylate de methyle * Methacrylsaeuremethyl ester * 2-(Methoxycarbonyl)-1-propene * Methylester kyseliny methakrylove * Methylmethacrylaat * Methyl-methacrylat * Methyl methacrylate * Methyl methacrylate monomer * Methyl methylacrylate * Methyl alpha-methylacrylate * Methyl 2-methyl-2-propenoate * 2-Methyl-2-propenoic acid methyl ester * Metil metacrilato * NCI-C50680 * Pegalan * 2-Propenoic acid, 2-methyl-, methyl ester * RCRA waste number U162
    80-62-6 SYNONYMS   : * Acrylic acid, 2-methyl-, methyl ester * Metakrylan metylu * Methacrylate de methyle * Methacrylsaeuremethyl ester * 2-(Methoxycarbonyl)-1-propene * Methylester kyseliny methakrylove * Methylmethacrylaat * Methyl-methacrylat * Methyl methacrylate * Methyl methacrylate monomer * Methyl methylacrylate * Methyl alpha-methylacrylate * Methyl 2-methyl-2-propenoate * 2-Methyl-2-propenoic acid methyl ester * Metil metacrilato * NCI-C50680 * Pegalan * 2-Propenoic acid, 2-methyl-, methyl ester * RCRA waste number U162 *** CHEMICAL IDENTIFICATION *** RTECS NUMBER : OZ5075000 CHEMICAL NAME : Methacrylic acid, methyl ester CAS REGISTRY NUMBER : 80-62-6 BEILSTEIN REFERENCE NO. : 0605459 REFERENCE : 4-02-00-01519 (Beilstein Handbook Reference) LAST UPDATED : 199803 DATA ITEMS CITED : 102 MOLECULAR FORMULA : C5-H8-O2 MOLECULAR WEIGHT : 100.13 WISWESSER LINE NOTATION : 1UY1&VO1COMPOUND DESCRIPTOR : Tumorigen Mutagen Reproductive Effector Human Primary Irritant SYNONYMS/TRADE NAMES : * Acrylic acid, 2-methyl-, methyl ester * Metakrylan metylu * Methacrylate de methyle * Methacrylsaeuremethyl ester * 2-(Methoxycarbonyl)-1-propene * Methylester kyseliny methakrylove * Methylmethacrylaat * Methyl-methacrylat * Methyl methacrylate * Methyl methacrylate monomer * Methyl methylacrylate * Methyl alpha-methylacrylate * Methyl 2-methyl-2-propenoate * 2-Methyl-2-propenoic acid methyl ester * Metil metacrilato * NCI-C50680 * Pegalan * 2-Propenoic acid, 2-methyl-, methyl ester * RCRA waste number U162 *** HEALTH HAZARD DATA *** ** SKIN/EYE IRRITATION DATA ** TYPE OF TEST : Open irritation test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 10 gm/kg REFERENCE : JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 23,343,1941 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 150 mg REFERENCE : INMEAF Industrial Medicine. (Chicago, IL) V.1-18, 1932-49. For publisher information, see IOHSA5. Volume(issue)/page/year: 14,292,1945 ** ACUTE TOXICITY DATA ** TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Human DOSE/DURATION : 125 ppm TOXIC EFFECTS : Behavioral - sleep Behavioral - excitement Behavioral - anorexia (human) REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 19(10),25,1954 TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Human DOSE/DURATION : 60 mg/m3 TOXIC EFFECTS : Behavioral - sleep Behavioral - excitement Vascular - BP lowering not characterized in autonomic section REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 1,56,1957 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 7872 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness Behavioral - coma Lungs, Thorax, or Respiration - respiratory depression REFERENCE : JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 23,343,1941 TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 78000 mg/m3/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, s...
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  • MSDS PAGE: MSDS 80-62-6 CAS Methyl-d3 methacrylate-d5, stabilized Deuterated methyl methacrylate monomer.
    80-62-6 SYNONYMS : Deuterated methyl methacrylate monomer. **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| |----------------|--------------------------------------|----------|-----------| |----------------|--------------------------------------|----------|-----------| | 35233-69-3 |Methyl-d3 methacrylate-d5 | >99 | 252-449-9 | +----------------+--------------------------------------+----------+-----------+ Text for R-phrases: see Section 16 Hazard Symbols: XI F Risk Phrases: 11 37/38 43 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Highly flammable. Irritating to respiratory system and skin. May cause sensitization by skin contact. Potential Health Effects Eye: Causes eye irritation. Vapors cause eye irritation. Lachrymator (substance which increases the flow of tears). Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May be absorbed through intact skin. Ingestion: May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes respiratory tract irritation. Inhalation of vapors at high concentrations may cause difficulty breathing and pulmonary edema. Overexposure produces central nervous system depression. May impair sense of smell. Chronic: Prolonged inhalation may cause respiratory tract inflammation and lung damage. Repeated exposure may cause tingling in the extremities and other nervous system abnormalities. **** SECTION 4 - FIRST AID MEASURES **** Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid. Skin: In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical aid if symptoms occur. Wash clothing before reuse. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Fire or excessive heat may result in violent rupture of the container due to bulk polymerization. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. This liquid floats on water and may travel to a source of ignition and spread fire. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Water may be ineffective because it will not cool material below its flash point. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation. **** SECTION 7 - HANDLING and STORAGE **** Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transf...
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  • MSDS PAGE: MSDS 80-62-6 CAS Methyl methacrylate, 99+% (GC) Methyl Methacrylate Monomer; Methacrylic Acid Methyl Ester; alpha-Methacrylic Acid.
    80-62-6 SYNONYMS : Methyl Methacrylate Monomer; Methacrylic Acid Methyl Ester; alpha-Methacrylic Acid. **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| | 80-62-6 |Methyl methacrylate | > 99 | 201-297-1 | +----------------+--------------------------------------+----------+-----------+ Hazard Symbols: XI F Risk Phrases: 11 37/38 43 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Highly flammable. Irritating to respiratory system and skin. May cause sensitization by skin contact.Corrosive.Light sensitive.Air sensitive.Heat sensitive. Potential Health Effects Eye: Contact with eyes may cause severe irritation, and possible eye burns. May cause eye injury. Skin: May cause severe skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Ingestion: May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause allergic reaction. Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause allergic respiratory reaction. May cause respiratory tract irritation. May cause effects similar to those described for ingestion. Chronic: Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. May cause reproductive and fetal effects. Repeated exposure may cause tingling in the extremities and other nervous system abnormalities. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Vapor may cause flash fire. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May polymerize explosively when involved in a fire. Containers may explode when heated. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in s...
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  • MSDS PAGE: MSDS 80-62-6 CAS Methyl methacrylate, 99%, stabilized with 10 - 20 ppm MEHQ Methyl methacrylate monomer; Methacrylic acid, methyl ester; MMA.
    80-62-6 SYNONYMS : Methyl methacrylate monomer; Methacrylic acid, methyl ester; MMA. **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** +----------------+--------------------------------------+----------+-----------+ | CAS# | Chemical Name | % | EINECS# | |----------------|--------------------------------------|----------|-----------| |----------------|--------------------------------------|----------|-----------| | 80-62-6 |Methyl methacrylate | 99 | 201-297-1 | |----------------|--------------------------------------|----------|-----------| | 150-76-5 |4-Methoxyphenol | .0015 | 205-769-8 | +----------------+--------------------------------------+----------+-----------+ Text for R-phrases: see Section 16 Hazard Symbols: XI F Risk Phrases: 11 37/38 43 **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Highly flammable. Irritating to respiratory system and skin. May cause sensitization by skin contact.Corrosive.Light sensitive.Air sensitive.Heat sensitive. Potential Health Effects Eye: Contact with eyes may cause severe irritation, and possible eye burns. May cause eye injury. Skin: May cause severe skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Ingestion: May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause allergic reaction. Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. May cause effects similar to those described for ingestion. Chronic: Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. May cause reproductive and fetal effects. Repeated exposure may cause tingling in the extremities and other nervous system abnormalities. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: **** SECTION 5 - FIRE FIGHTING MEASURES **** General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Vapor may cause flash fire. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May polymerize explosively when involved in a fire. Containers may explode when heated. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** ...
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  • MSDS PAGE: CAS 80-62-6 MSDS arkema-inc_com---414.asp
    80-62-6 File Name : arkema-inc_com---414.asp Plexiglas(R) Elit Sheet Material Safety Data Sheet Arkema Inc. 1 PRODUCT AND COMPANY IDENTIFICATION EMERGENCY PHONE NUMBERS: Atoglas Sheet Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887 Arkema Inc. Medical: Rocky Mountain Poison Control Center 2000 Market Street (866) 767-5089 (24Hrs) Philadelphia, PA 19103 Information Telephone Numbers Phone Number Available Hrs Atoglas Customer Service (800) 523-1532 8:00 am - 6:00pm EST Product Name Plexiglas(R) Elit Sheet Product Synonym(s) Chemical Family Acrylic Copolymer Chemical Formula N/A Chemical Name Acrylic Copolymer EPA Reg Num Product Use 2 COMPOSITION / INFORMATION ON INGREDIENTS Ingredient Name CAS RegistryNumber Typical Wt. % OSHA Acrylic Polymer Proprietary 99.2 MINIMUM N Methyl methacrylate 80-62-6 0.5 MAXIMUM Y The substance(s) marked with a "Y" in the OSHA column, are identified as hazardous chemicals according to the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200) While this material is not classified as hazardous under Federal OSHA regulations, this MSDS contains valuable information critical to the safe handling and proper use of this product. This MSDS should be retained and available for employees and other users of this product. The components of this product are all on the TSCA Inventory list. 3 HAZARDS IDENTIFICATION Emergency Overview Clear to opaque sheet in various colors. Odorless. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES. Potential Health Effects Inhalation and skin contact are expected to be the primary routes of occupational exposure to this material. As a finished product, it is a synthetic, high molecular weight polymer. Due to its chemical and physical properties, this material does not require special handling other than the good industrial hygiene and safety practices employed with any industrial material of this type. Under normal processing conditions, this material will release fume or vapor. Components of these releases may vary with processing time and temperatures. These process releases may produce eye, skin and/or respiratory tract irritation and, with repeated or prolonged exposures, nausea, drowsiness, headache and weakness. Product Code: 23446 Page 1 Revision: 11 Issued: 11 OCT 2004 of 6 Plexiglas(R) Elit Sheet Material Safety Data Sheet Arkema Inc. 4 FIRST AID MEASURES IF IN EYES, immediately flush with plenty of water. IN CASE OF CONTACT, flush the area with plenty of water. Remove material from clothing. Wash clothing before reuse. IF INHALED, remove to fresh air. 5 FIRE FIGHTING MEASURES Fire and Explosive Properties Auto-Ignition Temperature >400 C/752 F Flash Point NA Flash Point Method Flammable Limits- Upper NA NA Lower Extinguishing Media Use water spray, carbon dioxide, foam or dry chemical. Fire Fighting Instructions Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self-contained breathing apparatus (pressure demand NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Fire and Explosion Hazards Heated material can form flammable vapors with air. 6 ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Contain spill. Sweep or scoop up and remove to suitable container. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and/or hazardous waste disposal and other requirements listed in pertinent environmental permits. 7 HANDLING AND STORAGE Handling Avoid temperature extremes during storage; ambient temperature preferred. Storage Use only with adequate ventilation. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation if necessary to control exposure levels below airborne exposure limits (see below). If...
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  • MSDS PAGE: CAS 80-62-6 MSDS finishingequipco_com---FE_MSDS_Solidstrip.asp
    80-62-6 File Name : finishingequipco_com---FE_MSDS_Solidstrip.asp Solidstrip® Plastic Abrasives: ACRYLIC MATERIAL SAFETY DATA SHEET Section 1: Information Section 2: Ingredients Solidstrip Incorporated, Minocqua, Wisconsin Ingred.#CAS No. Exposure Limit Supplier: Ingredient Telephone For Product Information:715-356-7130 ACGIH None Acrylic Polymer None Product: Acrylic Plastic OSHA None Section 3: Physical Data Section 4: Fire and Explosion Data Evaporation Rate: Solid Flash Point, ASTM D-1929: Estimated Flash Approx. 391 C Vapor Density: N/A Extinguishing Media: Foam, Carbon Dioxide, Water, Dry Chemical Solubility in Water: Insoluble Unusual Fire & Explosion Hazards: None Percent Volatile: N/A Approximate Flammable Limits: N\A Approximate Boiling Range: N/A Special Fire Fighting Procedures: Full protective equipment. Density: 1.19 Section 5: Health Hazard Data Symptoms/Effects of Overexposure and First Aid Ingestion: Ingestion of small quantities of this material under normal circumstances would not cause harmful effect. Inhalation: Gross overexposure to nuisance particles, regardless of how generated, may cause irritation of the respiratory tract. If irritation develops, remove to fresh air. If breathing difficulty persists, consult a physician. Skin or Eye Contact: Nuisance particles may cause irritation. In case of eye contact, flush immediately with large amounts of water. For skin, wash with soap and water. If irritation persists, consult a physician. Section 6: Reactivity Data Stability: Stable Conditions to Avoid: Sources of ignition and temperatures above 570 F or 370 C. Incompatibility: N/A Hazardous Decomposition: Under fire conditions, hazardous decomposition products will include: CO, CO2 and smoke. Temperatures above 370 C can cause methyl methacrylate monomer (MMA) to be released. See section 8. Exposure Limits Cas Number Vapor Pressure OSHA & ACGIH MMA 100ppm 80-62-6 29mm (20 C) Vapor may cause irritation to the eyes, nose and throat. May cause central nervous system effects such as dizziness, headache, nausea and loss of consciousness. Under some circumstances, mutagenic changes have been observed with MMA. The meaning and significance of these results is not understood. At 1000 ppm, MMA is weakly embryotoxic with rats. Hazardous Polymerization: Will not occur. Section 7: Spill or Leak Procedures Steps to be Taken in Case of Spill: No special procedures required. Waste Disposal Method: Sanitary landfill; in accordance with Federal, State and Local Regulations. Section 8: Special Protections Information Section 9: Special Precautions Respiratory: Do not breath dust. Wear a properly fitted dust Handling and Storing: N/A respirator approved by NIOSH/MSHA during application, unless Other: N/A air monitoring shows dust levels below 10mg/m3. Transportation: Not Regulated. Ventilation: Provide sufficient ventilation in volume and pattern to keep airborne levels of methyl methacrylate below 100ppm and dust levels below 10mg/m3. Protective Gloves: Leather gloves are recommended. Eye Protection: Safety glasses with side shields. (MSDS-SPA): Acrylic Solidstrip® Plastic Abrasives: MELAMINE MATERIAL SAFETY DATA SHEET Section 1: Information Section 2: Ingredients Supplier: Solidstrip Incorporated, Minocqua, Wisconsin Ingred.#CAS No. Exposure Limit Ingredient Telephone For Product Information:715-356-7130 ACGIH None Melamine Formaldehyde None Product: Melamine Plastic OSHA None Cellulosate Section 3: Physical Data Section 4: Fire and Explosion Data Evaporation Rate: Solid Flash Point, ASTM D-1929: Estimated Flash Approx. 391 C Vapor Density: N/A Extinguishing Media: Foam, Carbon Dioxide, Water, Dry Chemical Solubility in Water: Insoluble Unusual Fire & Explosion Hazards: None Percent Volatile: N/A Approximate Flammable Limits: N\A Approximate Boiling Range: N/A Special Fire Fighting Procedures: Full protective equipment. Density: 1.51 Section 5: Health Hazard Data Symptoms/Effects of Overexposure and First Aid Ingestion: In...
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  • MSDS PAGE: CAS 140-88-5 80-62-6 MSDS plexiglas_com---5.asp
    80-62-6 File Name : plexiglas_com---5.asp PLEXIGLAS (R) V052-100 Acrylic Resin Material Safety Data Sheet Arkema Inc. 1 PRODUCT AND COMPANY IDENTIFICATION EMERGENCY PHONE NUMBERS: Altuglas International Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887 Arkema Inc. Medical: Rocky Mountain Poison Control Center 2000 Market Street (866) 767-5089 (24Hrs) Philadelphia, PA 19103 Information Telephone Numbers Phone Number Available Hrs Altuglas International Customer Service (800) 523-1532 8:00 am - 6:00pm EST Product Name PLEXIGLAS (R) V052-100 Acrylic Resin Product Synonym(s) Chemical Family Acrylic Copolymer Chemical Formula N/A Chemical Name See Ingredients EPA Reg Num Product Use 2 COMPOSITION / INFORMATION ON INGREDIENTS Ingredient Name CAS RegistryNumber Typical % OSHA Ethyl acrylate 140-88-5 0.1 Y Methyl methacrylate 80-62-6 0.7 Y P(EA/MMA) Proprietary 99.3 N The substance(s) marked with a "Y" in the OSHA column, are identified as hazardous chemicals according to the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200) While this material is not classified as hazardous under Federal OSHA regulations, this MSDS contains valuable information critical to the safe handling and proper use of this product. This MSDS should be retained and available for employees and other users of this product. The components of this product are all on the TSCA Inventory list. 3 HAZARDS IDENTIFICATION Emergency Overview Clear cololesr pellets with mild odor CAUTION! MELT PROCESSING RELEASES VAPORS WHICH MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION Potential Health Effects Skin contact and inhalation of dust are expected to be the primary routes of occupational exposure to this material. As a finished product, it is a synthetic, high molecular weight polymer pellet. Due to its chemical and physical properties, this material does not require special handling other than the good industrial hygiene and safety practices employed with any industrial material of this type. Ethyl acrylate is classified as possibly carcinogenic to humans (Group 2B) by the International Agency for Research on Cancer (IARC). Product Code: 14916 Page 1 Revision: 11 Issued: 03 MAY 2005 of 6 PLEXIGLAS (R) V052-100 Acrylic Resin Material Safety Data Sheet Arkema Inc. 4 FIRST AID MEASURES IF IN EYES, immediately flush with plenty of water. Get medical attention if irritation persists. IN CASE OF CONTACT, flush the area with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops and persists. IF INHALED, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. 5 FIRE FIGHTING MEASURES Fire and Explosive Properties Auto-Ignition Temperature 393 C/739 F Flash Point NA Flash Point Method Flammable Limits- Upper NA NA Lower Extinguishing Media Use water spray, carbon dioxide, foam or dry chemical. Fire Fighting Instructions Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self-contained breathing apparatus (pressure demand NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Fire and Explosion Hazards Heated material can form flammable vapors with air. 6 ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Contain spill. Sweep or scoop up and remove to suitable container. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and/or hazardous waste disposal and other requirements listed in pertinent environmental permits. 7 HANDLING AND STORAGE Handling Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Storage Avoid temperature extremes during storage; ambient temperature preferred. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering...
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  • MSDS PAGE: CAS 5232-99-5 80-62-6 MSDS buehler_com---9101795EU.asp
    80-62-6 File Name : buehler_com---9101795EU.asp |-------------------------------------| | SAFETY DATA SHEET | |-------------------------------------| |=========================================================================| | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |=========================================================================| PRODUCT NAME : BUEHLER PLASTIC LIQUID IDENTIFICATION NUMBER: 20-3554, 20-3550 PRODUCT USE/CLASS : Acrylic SUPPLIER: Buehler UK, Ltd. Buehler GmbH Saturn Building In der Steele 2, 40599 Düsseldorf 101, Lockhurst Lane Postfach 16 03 55, 40599 Düsseldorf Coventry CV6 5SF ENGLAND TEL: (+44) (0) 24 7658 2158 Telefon: (+49) 0211-974100 FAX: (+44) (0) 24 7658 2159 Telefax: (+49) 0211-9741079 PREPARER: Technical Department, PHONE: +18472955600, PREPARE DATE: 04/04/01 |=========================================================================| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |=========================================================================| ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT% --------------------------------------------------------------------------- 01 Ethyl-2-cyano-3,3-diphenyl acrylate 5232-99-5 1.0-5.0 Classification: No information; N.E. 02 Methyl methacrylate 80-62-6 60.0-100.0 Classification: F, Xi; R11-36/37/38-43 ---------------------- EXPOSURE LIMITS -------------------- U/K GERMANY OTHER ITEM 8-HR REL 15-MIN STEL 8-HR MAK 15-MIN MAK 8-HR TWA SKIN --------------------------------------------------------------------------- 01 N.E. N.E. N.E. N.E. 10 mg/m3 NO 02 50 ppm 100 ppm 50 ppm N.E. 50ppm ACGIH NO (See Section 16 for abbreviation legend) |=========================================================================| | SECTION 3 - IDENTIFICATION OF HAZARDS | |=========================================================================| EMERGENCY OVERVIEW: (R11) Highly flammable. (R43) May cause sensitisation by skin contact. (R36/37/38) Irritating to eyes, respiratory system, and skin. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT, |=========================================================================| | SECTION 4 - FIRST AID MEASURES | |=========================================================================| EYE CONTACT: Flush eye with water for 15 minutes. Get medical attention. SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. INHALATION: If symptoms occur, remove to fresh air. Medical personnel may administer oxygen if breathing is difficult. Seek medical attention if symptoms persist. INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. NOTES TO PHYSICIAN: Not Applicable. Continued on Page 2) =========================================================================== BUEHLER SAFETY DATA SHEET 9101795EU Product: 20-3554, 20-3550 Preparation Date: 04/04/01 Page 2 |=========================================================================| | SECTION 5 - FIRE FIGHTING MEASURES | |=========================================================================| FLASH POINT: 10 C LOWER EXPLOSIVE LIMIT: 2.1 % (TAGLIABUE CLOSED CUP) UPPER EXPLOSIVE LIMIT: 12.5 % AUTOIGNITION TEMPERATURE: No data EXTINGUISHING MEDIA:ALCOHOL FOAM,CO2,DRY CHEMICAL,FOAM,WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air, and may travel along the ground to be reignited at locations distant from the source; flashback of flame may occur. Containers exposed to fire may explode. SPECIAL FIREFIGHTING PROCEDURES: Use full protective clothing. Water spray may be used to cool exposed containers but is not recommended for fire. |=========================================================================| | SECTION 6 - ACCIDENTAL RELEASE MEASURES | |=========================================================================| S...
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  • MSDS PAGE: CAS 5232-99-5 80-62-6 MSDS buehler_com---9107495.asp
    80-62-6 File Name : buehler_com---9107495.asp |-------------------------------------------------------| | MATERIAL SAFETY DATA SHEET | |-------------------------------------------------------| |=========================================================================| | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |=========================================================================| PRODUCT NAME : BUEHLER PLASTIC LIQUID& KIT, VARIDUR LIQUID & KIT IDENTIFICATION NUMBER: 20-3550, 20-3554, 20-3570, 20-3574, 20-3578 PRODUCT USE/CLASS : Acrylic SUPPLIER: Buehler, Ltd. 41 Waukegan Road Lake Bluff, IL 60044 EMERGENCY: 800-424-9300 INFORMATION: 847-295-6500 PREPARER: Technical Department, PHONE: 847-295-6500, PREPARE DATE: 05/22/06; 22 May 06 |=========================================================================| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |=========================================================================| ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT% --------------------------------------------------------------------------- 01 Ethyl-2-cyano-3,3-diphenyl acrylate 5232-99-5 1.0-5.0 02 Methyl methacrylate 80-62-6 60.0-100.0 ---------------------- EXPOSURE LIMITS -------------------- ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN --------------------------------------------------------------------------- 01 N.E. N.E. N.E. N.E. 10 mg/m3 NO 02 100 ppm N.E. 100 ppm N.E. N.E. NO (See Section 16 for abbreviation legend) |=========================================================================| | SECTION 3 - HAZARDS IDENTIFICATION | |=========================================================================| EMERGENCY OVERVIEW: Harmful if inhaled or swallowed. Causes skin and eye irritation. Inhalation of vapors may cause respiratory irritation. Potential skin sensitizer. ACUTE EFFECTS - EYE CONTACT: Moderately irritating to the eyes. ACUTE EFFECTS - SKIN CONTACT: Contact causes skin irritation. Repeated orprolonged overexposure may cause allergic response. ACUTE EFFECTS - INHALATION: May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. ACUTE EFFECTS - INGESTION: This material may be harmful or fatal if swallowed. Irritating to mouth, throat and stomach, with nausea. Ingestion of significant amounts may cause kidney damage. CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological disorders may be aggravated by exposure to hazardous components. OTHER INFORMATION: *Overexposure to hazardous components may aggravate preexisting skin, lung, or kidney disorders. *Repeated and prolonged overexposure may cause damage to the liver or kidneys. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT, Continued on Page 2) =========================================================================== 9107495 Product: 20-3554, 20-3550,20-3572,20-3570,20-3576 Preparation Date: 05/22/06; 22 May 06 Page 2 |=========================================================================| | SECTION 4 - FIRST AID MEASURES | |=========================================================================| EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Remove contaminated clothing. Wash skin with soap and water. Get medical attention. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. NOTES TO PHYSICIAN: Not Applicable. |=========================================================================| | SECTION 5 - FIRE FIGHTING MEASURES | |=========================================================================| FLASH POINT: 50 F LOWE...
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  • MSDS CAS# 80-62-6 140-88-5 80-62-6_v3.asp
    80-62-6 140-88-5 File Name : 80-62-6_v3.asp PLEXTUF 2000-101 (R) Acrylic Resin Material Safety Data Sheet Arkema Inc. 1 PRODUCT AND COMPANY IDENTIFICATION EMERGENCY PHONE NUMBERS: Atoglas Resin Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887 Arkema Inc. Medical: Rocky Mountain Poison Control Center 2000 Market Street (866) 767-5089 (24Hrs) Philadelphia, PA 19103 Information Telephone Numbers Phone Number Available Hrs Atoglas Customer Service (800) 523-1532 8:00 am - 6:00pm EST Product Name PLEXTUF 2000-101 (R) Acrylic Resin Product Synonym(s) Chemical Family Acrylic Copolymer Chemical Formula N/A Chemical Name See Ingredients EPA Reg Num Product Use 2 COMPOSITION / INFORMATION ON INGREDIENTS Ingredient Name CAS RegistryNumber Typical Wt. % OSHA Acrylic Copolymers Proprietary 99.5 N Methyl methacrylate 80-62-6 0.5 Y Ethyl acrylate 140-88-5 0.1 Y The substance(s) marked with a "Y" in the OSHA column, are identified as hazardous chemicals according to the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200) While this material is not classified as hazardous under Federal OSHA regulations, this MSDS contains valuable information critical to the safe handling and proper use of this product. This MSDS should be retained and available for employees and other users of this product. The components of this product are all on the TSCA Inventory list. 3 HAZARDS IDENTIFICATION Emergency Overview Clear pellets with mild odor CAUTION! MELT PROCESSING RELEASES VAPORS WHICH MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION Potential Health Effects Skin contact and inhalation of dust are expected to be the primary routes of occupational exposure to this material. As a finished product, it is a synthetic, high molecular weight polymer pellet. Due to its chemical and physical properties, this material does not require special handling other than the good industrial hygiene and safety practices employed with any industrial material of this type. Ethyl acrylate is classified as possibly carcinogenic to humans (Group 2B) by the International Agency for Research on Cancer (IARC). Product Code: 13234 Page 1 Revision: 10 Issued: 11 OCT 2004 of 6 PLEXTUF 2000-101 (R) Acrylic Resin Material Safety Data Sheet Arkema Inc. 4 FIRST AID MEASURES IF IN EYES, immediately flush with plenty of water. IN CASE OF CONTACT, flush the area with plenty of water. Remove material from clothing. Wash clothing before reuse. IF INHALED, remove to fresh air. 5 FIRE FIGHTING MEASURES Fire and Explosive Properties Auto-Ignition Temperature 393 C/739 F Flash Point NA Flash Point Method Flammable Limits- Upper NA NA Lower Extinguishing Media Use water spray, carbon dioxide, foam or dry chemical. Fire Fighting Instructions Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self-contained breathing apparatus (pressure demand NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Fire and Explosion Hazards Heated material can form flammable vapors with air. 6 ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Contain spill. Sweep or scoop up and remove to suitable container. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and/or hazardous waste disposal and other requirements listed in pertinent environmental permits. 7 HANDLING AND STORAGE Handling Avoid breathing dust and processing vapors. Process using adequate ventilation. Storage Avoid temperature extremes during storage; ambient temperature preferred. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation if necessary to control exposure levels below airborne exposure limits (see below). If practical, use local mechanical exhaust ventilation at sources of air contam...
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  • MSDS CAS# 57-11-4 140-88-5 80-62-6 57-11-4_v1.asp
    80-62-6 File Name : 57-11-4_v1.asp PLEXIGLAS(R) VH-100 Acrylic Resin Material Safety Data Sheet Arkema Inc. 1 PRODUCT AND COMPANY IDENTIFICATION EMERGENCY PHONE NUMBERS: Atoglas Resin Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887 Arkema Inc. Medical: Rocky Mountain Poison Control Center 2000 Market Street (866) 767-5089 (24Hrs) Philadelphia, PA 19103 Information Telephone Numbers Phone Number Available Hrs Atoglas Customer Service (800) 523-1532 8:00 am - 6:00pm EST Product Name PLEXIGLAS(R) VH-100 Acrylic Resin Product Synonym(s) Chemical Family Acrylic Copolymer Chemical Formula N/A Chemical Name See Ingredients EPA Reg Num Product Use 2 COMPOSITION / INFORMATION ON INGREDIENTS Ingredient Name CAS RegistryNumber Typical Wt. % OSHA P(EA/MMA) Proprietary 98-99 N Stearic acid 57-11-4 1-2 Y Ethyl acrylate 140-88-5 0.1 Y Methyl methacrylate 80-62-6 0.1 Y The substance(s) marked with a "Y" in the OSHA column, are identified as hazardous chemicals according to the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200) While this material is not classified as hazardous under Federal OSHA regulations, this MSDS contains valuable information critical to the safe handling and proper use of this product. This MSDS should be retained and available for employees and other users of this product. The components of this product are all on the TSCA Inventory list. 3 HAZARDS IDENTIFICATION Emergency Overview Various color pellets with mild odor CAUTION! MAY CAUSE EYE AND SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. Potential Health Effects Skin contact and inhalation of dust are expected to be the primary routes of occupational exposure to this material. As a finished product, it is a synthetic, high molecular weight polymer pellet. Due to its chemical and physical properties, this material does not require special handling other than the good industrial hygiene and safety practices employed with any industrial material of this type. Product Code: 12941 Page 1 Revision: 9 Issued: 03 NOV 2004 of 6 PLEXIGLAS(R) VH-100 Acrylic Resin Material Safety Data Sheet Arkema Inc. Stearic acid Ethyl acrylate is classified as possibly carcinogenic to humans (Group 2B) by the International Agency for Research on Cancer (IARC). 4 FIRST AID MEASURES IF IN EYES, immediately flush with plenty of water. Get medical attention if irritation persists. IN CASE OF CONTACT, flush the area with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops and persists. IF INHALED, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. 5 FIRE FIGHTING MEASURES Fire and Explosive Properties Auto-Ignition Temperature 393 C/739 F Flash Point NA Flash Point Method Flammable Limits- Upper NA NA Lower Extinguishing Media Use water spray, carbon dioxide, foam or dry chemical. Fire Fighting Instructions Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self-contained breathing apparatus (pressure demand NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Fire and Explosion Hazards Heated material can form flammable vapors with air. 6 ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Contain spill. Sweep or scoop up and remove to suitable container. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and/or hazardous waste disposal and other requirements listed in pertinent environmental permits. 7 HANDLING AND STORAGE Handling Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Storage Avoid temperature extremes during storage; ambient temperature preferred. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls Inv...
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  • MSDS CAS# 80-62-6 2082-81-7 116-17-6 99-97-8 80-62-6.asp
    80-62-6 2082-81-7 116-17-6 99-97-8 File Name : 80-62-6.asp MATERIAL SAFETY DATA SHEET 03130 Pg. 1 1. Chemical Product and Contact Information Issued: 11/19/07 LECOSET 7007 Product Name: HAZ Part Numbers: Liquid 813-003 813-003-HAZ LECO Corporation 813-003-010 813-055 3000 Lakeview 813-055-HAZ 813-055-010 St. Joseph, Michigan 49085 813-102-HAZ 813-107-HAZ Information: 269-983-5531 KIT: Chemtrec: 800-424-9300 813-001 813-001-HAZ (Chemtrec Int'l: 703-527-3887) 813-001-010 813-091 813-091-HAZ 813-101-HAZ 2. Composition/Information on Ingredients OSHA ACGIH Typical % Component CAS No. PEL (mg/m3) TLV (mg/m3) by Weight Methyl Methacrylate 80-62-6 410 410 94 - 96 Monomer, Stabilized 1,4-butanedioldi- 2082-81-7 Not avail. Not avail. 3 methacrylate Phosphorous acid 116-17-6 Not avail. Not avail. 0.8 triisopropylester N, N-dimethyl-p- 99-97-8 Not avail. Not avail. 0.7 toluidine 3. Hazard Identification EMERGENCY OVERVIEW Serious fire and spill hazard; serious inhalation/skin absorption health risk. Yellowish liquid with a distinctive ester-like odor. Potential Health Effects EYES: Vapor or mist is irritating. SKIN: Irritating. May cause sensitization. INHALATION: Vapor or mist is irritating to mucous membranes and upper respiratory tract. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. INGESTION: Harmful if swallowed. MEDICAL CONDITIONS AGGRAVATED: May cause allergic respiratory and skin reactions. CHRONIC OVEREXPOSURE: Not available. ACUTE OVEREXPOSURE: Prolonged exposure can cause narcotic effect. CARCINOGENICITY: None. P/N: 813-003 MATERIAL SAFETY DATA SHEET 03130 Pg. 2 4. First Aid Measures EYES: Rinse immediately with opened lid for 15 minutes with plenty of running water and seek medical advice. SKIN: Immediately take off all contaminated clothing and wash skin with plenty of water. After contact with skin, wash immediately with polyethylene glycol 300 / ethyl alcohol 2:1 and rinse with plenty of water and soap. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. INGESTION: Wash out mouth with water provided person is conscious. Call a physician. 5. Fire Fighting Measures FLAMMABLE PROPERTIES: Flammable. Flash Point: 50° F. (10° C.) Method Used: Not given. Flammable Limits (% by Volume in Air, 77° F. (25° C.), 1011 mbar): Lower: 2.1 Upper: 12.5 AUTO-IGNITION TEMPERATURE: 815° F. (430° C.) HAZARDOUS COMBUSTION PRODUCTS: Toxic fumes of carbon monoxide, carbon dioxide. EXTINGUISHING MEDIA: Carbon dioxide, dry chemical powder, alcohol or polymer foam. FIREFIGHTING INSTRUCTIONS: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Use water spray to cool fire-exposed containers. Flammable liquid. Vapor may travel considerable distance to source of ignition and flash back. May undergo polymerization. Container explosion may occur under fire conditions. 6. Accidental Release Measures SMALL/LARGE SPILL: Evacuate area. Shut off all sources of ignition. Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Cover with an activated carbon adsorbent, take up and place in closed containers. Transport outdoors. Ventilate area and wash spill site after material pickup is complete. 7. Handling and Storage HANDLING: Fill only 80% of the container. Maintain well-ventilated working place and/or exhaust filter. Do not breathe vapors. Do not get in eyes, on skin or on clothing. Avoid prolonged or repeated exposure. Wash thoroughly after handling. Corrosive, Lachrymator, Sensitizer. It is advisable to use material within six months. STORAGE: Keep container closed. Keep away from heat, sparks and open flame. Refrigerate. Do not store under inert atmosphere. 8. Exposure Controls/Personal Protection ENGINEERING CONTROLS: Use efficient local ventilation. RESPIRATORY PROTECTION: Use approved respirator, if exposed to vapors. SKIN ...
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  • MSDS CAS# 80-62-6 2082-81-7 109-16-0 80-62-6_v1.asp
    80-62-6 2082-81-7 109-16-0 File Name : 80-62-6_v1.asp MATERIAL SAFETY DATA SHEET 03180 Pg. 1 Revised: 6/1/94 1. Chemical Product and Contact Information Product Name: Lecoset 5000 Liquid P/N:813-060 LECO Corporation 3000 Lakeview St. Joseph, MI, 49085 Information: 269-983-5531 Chemtrec: 800-424-9300 (Chemtrec Int'l: 202-483-2616) 2. Composition/Information on Ingredients OSHA ACGIH Other Typical % Component CAS No. PEL (ppm) TLV (ppm) Limits by Weight Methyl Methacrylate 80-62-6 100 100 8-hour TWA > 50 1,4-Butanedioldimeth- 2082-81-7 Not avail. Not avail. 10 - 20 acrylate Aromatic Epoxy- Not avail. Not avail. Not avail. 10 - 20 acrylate Triethyleneglycoldi- 109-16-0 Not avail. Not avail. 10 methacrylate 3. Hazard Identification EMERGENCY OVERVIEW Highly flammable; Irritating to eyes, respiratory system and skin. Clear, slightly yellowish liquid with distinctive ester-like odor. Potential Health Effects EYES: Can be irritating. SKIN: Can be irritating. May cause sensitization by contact INHALATION: Can be irritating. INGESTION: Not available. MEDICAL CONDITIONS AGGRAVATED: Not available. CHRONIC OVEREXPOSURE: Not available. ACUTE OVEREXPOSURE: Not available. CARCINOGENICITY: None. P/N: 813-060 MATERIAL SAFETY DATA SHEET 03180 Pg. 2 4. First Aid Measures EYES: Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. SKIN: Instantly wash with water and soap and rinse thoroughly. INHALATION: Supply fresh air and call for doctor for safety reasons. In case of unconsciousness bring patient into stable side position for transport. INGESTION: Initiate vomiting and consult a doctor. 5. Fire Fighting Measures FLAMMABLE PROPERTIES: Flammable. Flash Point: 50° F. (10° C.) Method Used: Not applicable. Flammable Limits (% by Volume in Air): Lower: 2.1 Upper: 12.5 AUTO-IGNITION TEMPERATURE: Not applicable. HAZARDOUS COMBUSTION PRODUCTS: Toxic fumes of carbon monoxide and carbon dioxide. EXTINGUISHING MEDIA: Use carbon dioxide, dry powder extinguisher, or foam. Do not use direct water jet. FIREFIGHTING INSTRUCTIONS: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Keep fire-exposed containers cool with water. Flammable liquid. Vapor may travel considerable distance to source of ignition and flash back. May undergo autopolymerization. Container explosion may occur under fire conditions. 6. Accidental Release Measures SMALL/LARGE SPILL: Evacuate area. Shut off all sources of ignition. Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Take up carefully with absorbent material (diatomaceous earth, sand, universal binding), dispose of correctly. 7. Handling and Storage HANDLING: Protect against physical damage. Separate from oxidizing materials. Do not breathe vapor; do not get in eyes, on skin or on clothing. Avoid prolonged/repeated exposure. Wash thoroughly after handling. Corrosive/Lachyrmator/Sensitizer. Keep away from heat, sparks and open flame. Fill container only 80%. Provide good ventilation of the room or workplace STORAGE: Keep container closed. Outside or detached storage is preferable. Inside storage should be in a standard flammable liquids storage room or cabinet. Separate from oxidizing materials. Do not store above 77° F. (25° C.). Keep away from sources of ignition, protect from light. 8. Exposure Controls/Personal Protection ENGINEERING CONTROLS: As required to maintain exposure limits. RESPIRATORY PROTECTION: NIOSH/MSHA approved respirator. SKIN AND HAND PROTECTION: Heavy rubber gloves. EYE AND FACE PROTECTION: Chemical safety goggles. OTHER PROTECTIVE EQUIPMENT: Face shield (8-inch minimum), safety shower and eye bath. P/N: 813-060 MATERIAL SAFETY DATA SHEET 03180 Pg. 3 9. Physical and Chemical Properties APPEARANCE: Clear, slightly yellowish. BOILING POINT: 212° F. (100° C.) FREEZE-MELT POINT: -54° F. (-48° C.) VAPOR PRESSURE (mm): 29 @ 68° F. (20° C.) VAPOR DENSITY (air = 1): 1.2 @ 100° F. (38° C.) SOLU...
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  • MSDS CAS# 80-62-6 103-11-7 38668-48-3 14808-60-7 80-62-6_v2.asp
    80-62-6 103-11-7 38668-48-3 14808-60-7 File Name : 80-62-6_v2.asp Alsan RS 288 Finish HMIS H =2 F=3 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION R=2 PPE = See Sec. 8 PRODUCT NAME.....?: Soprema Alsan RS 288 Finish PRODUCT CODE..........: RS060, RS061, RS062, RS063, RS064 PRODUCT CLASS…??.: Liquid-applied Waterproofing System - Component CHEMICAL FAMILY?: Solution of polymers dispersed in (meth)acrylic -monomers Soprema S.A. EMERGENCY TELEPHONE NUMBERS: 14, rue de Saint Nazaire ? BP 121 (for transportation incidents only) F-67025 Strasbourg CEDEX 1 CHEMTREC (USA): (800) 424-9300 France CANUTEC (Canada): (613) 996-6666 International: (703) 527-3887 Poison Control Center: Contact local telephone directory DISTRIBUTOR: Soprema, Inc. 310 Quadral Drive Wadsworth, OH 44281 Ph: (800) 356-3521 2. COMPOSITION/ INFORMATION ON INGREDIENTS ACGIH OSHA Component CAS# % By Weight TLV PEL 3 Methyl methacrylate 80-62-6 > 25 50 205 mg/m 50 ppm 100 ppm 82 mg/m3 2-Ethylhexyl acrylate 103-11-7 > 10 25 10 ppm N/A Other acrylates Confidential >15 N/A 100 ppm 1,1'-(p-Tolylimino)- dipropan- 38668-48-3 > 0.5 1.0 N/A N/A 2- ol 3 3 0.05 mg/m 10 mg/m Quartz 14808-60-7 5 (as respirable quartz dust) %SiO2+2 TSCA: all ingredients are listed 1,1?-(p-Tolylimino)-dipropan-2-ol, which is toxic when ingested or 3. HAZARD IDENTIFICATION inhaled (no target organ provided - see Section 11. Toxicological Information). POTENTIAL HEALTH EFFECTS: Crystalline silica as Quartz, which may cause mechanical irritation of the ROUTE(S) OF ENTRY: Skin and eye contact with liquids, and eyes. High concentrations of dust may cause coughing and mild, inhalation. temporary irritation. Quartz dust can accumulate in the lungs. Prolonged or repeated exposure to fine airborne crystalline silica dust may cause HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE: This severe scarring of the lungs, a disease called silicosis. However, this product is toxic when inhaled or ingested and can cause skin, eye and product is sold as a liquid preparation and, when used as intended, does not respiratory irritation as well as skin and respiratory sensitization. generate dust. Thus the product as such does not pose a respiration hazard attributable to these components. This product contains: CARCINOGENICITY: Methyl methacrylat e and 2-Ethylhexyl acrylate, which may cause skin, NTP..............: Yes (Quartz ? See Section 3) eye and respiratory irritation. High concentrations can cause symptoms IARC............: Yes (Quartz ? See Section 3) of central nervous system depression, such as headache, nausea, OSHA...........: No dizziness, drowsiness, and confusion. Both acrylates can cause dermal and respiratory sensitization. Once a person is sensitized contact with 4. FIRST AID MEASURES: even a small amount may cause outbreaks of dermatitis with symptoms such as skin redness, itching, rash and swelling. This can spread from SKIN: Remove contaminated clothing and shoes. Wash with soap or the hands or arms to other parts of the body. Persons with respiratory mild detergent and large amounts of water. Do not use solvents or sensitization can experience symptoms of bronchial asthma such as thinners. Get medical attention if irritation occurs. Wash clothing before wheezing, difficult breathing, sneezing and runny or blocked nose at re-use. low airborne concentrations that have no effect on un-sensitized people. EYES: Hold eyes open and flush for at least 15 minutes with large Other acrylates, which may cause skin eye and respiratory irritation and amounts of water. Seek medical attention. sensitization. SOPREMA, INC., LIQUID DIVISION, 310 QUADRAL DRIVE, WADSWORTH, OH, USA 44281 Tel: 1-330-334-0066 Fax: (330) 334-4289 y www.soprema.us Page 1 of 2 Alsan RS 288 Finish INGESTION: Do not induce vomiting. Give two glasses of water to 10. STABILITY AND REACTIVITY dilute stomach contents. Never give anything by mouth to an un- conscious person. Consult physician immediately. CHEMICAL STABILITY: Stable. INHALATION: R...
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  • MSDS Methyl methacrylate CAS 80-62-6 MSDS
    80-62-6 SYNONYMS   : Section 1 - Chemical Product and Company Identification MSDS Name: Methyl methacrylate Catalog Numbers: AC127140000, AC127140010, AC127140025, AC127140250, AC414520000, AC414520030, AC414525000, EK1197979, EK1197987, O3629-4 Synonyms: Methacrylic acid, methyl ester; MMA; Methyl 2-methylpropenoate. Company Identification:               Fisher Scientific               1 Reagent Lane               Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS# Chemical Name Percent EINECS/ELINCS 80-62-6 Methyl methacrylate 99 201-297-1 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: APHA: 10 max liquid. Flash Point: 8 deg C. Danger! Flammable liquid and vapor. Causes eye, skin, and respiratory tract irritation. May cause sensitization by skin contact. Target Organs: Blood, kidneys, central nervous system, liver, spleen, respiratory system, eyes, skin. Potential Health Effects Eye: Causes eye irritation. Lachrymator (substance which increases the flow of tears). Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May be absorbed through the skin. Cross-reactivity to other methacrylates has been reported in individuals allergic to this material. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. May cause narcotic effects in high concentration. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. There are a number of reports of MMA respiratory sensitization and asthma under a variety of exposure conditions, but the results (even after chronic exposures at 100 ppm TWA) are remarkably varied and seem to involve no more than 0.4% of the population. (Documentation of the TLV) Chronic: Prolonged or repeated skin contact may cause dermatitis. May cause liver and kidney damage. Repeated exposure may cause damage to the spleen. Adverse reproductive effects have been reported in animals. Laboratory experiments have resulted in mutagenic effects. May cause lung damage. Chronic exposure may cause blood effects. Section 4 - First Aid Measures Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Call a poison control center. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors ca...
    http://www.chemcas.org/drug/analytical/cas/80-62-6.asp
      
      
      
    ALL PAGES On Chemical Properties IN THIS GROUP
    NameCASSynonymsMolecular FormulaMolecular Weight
    Maleic hydrazide 123-33-1 1,2-dihydropyridazine-3,6-dioneC4H4N2O2112.027
    Malonaldehyde, sodium salt 24382-04-5 sodium (1E)-3-oxoprop-1-en-1-olateC3H5O2Na96.019
    Manganese ethylenebisthiocarbamate 12427-38-2 [ethane-1,2-diylbiscarbamodithioato(2-)-kappaS]manganeseC4H6N2S4Mn264.879
    Manganese (II) sulfate monohydrate 10034-96-5 manganese(2+) sulfate hydrateH2O5SMn164.869
    Manidipine.2HCl 89226-75-5 3,5-Pyridinedicarboxylic acid, 1,4-dihydro-2,6-dimethyl-4-(3-nitrophenyl)-, 2-(4-(diphenylmethyl)-1-piperazinyl)ethyl methyl ester, dihydrochlorideC35H40N4O6Cl2682.232
    d-Mannitol 69-65-8 D-mannitolC6H14O6182.079
    Mannitol nitrogen mustard 576-68-1 (2R,3R,4R,5R)-1,6-bis[(2-chloroethyl)amino]hexane-2,3,4,5-tetrolC10H22N2O4Cl2304.096
    MeIQ 77094-11-2 3,4-dimethyl-3H-imidazo[4,5-f]quinolin-2-amineC12H12N4212.106
    MeIQx 77500-04-0 3,8-dimethyl-3H-imidazo[4,5-f]quinoxalin-2-amineC11H11N5213.101
    Melamine 108-78-1 1,3,5-triazine-2,4,6-triamineC3H6N6126.065
    Melphalan 148-82-3 4-[bis(2-chloroethyl)amino]-L-phenylalanineC13H18N2O2Cl2304.075
    dl-Menthol 15356-70-4 2-isopropyl-5-methylcyclohexanolC10H20O156.151
    MER-25 67-98-1 1-{4-[2-(diethylamino)ethoxy]phenyl}-2-(4-methoxyphenyl)-1-phenylethanolC27H33NO3419.246
    2-Mercaptobenzothiazole 149-30-4 1,3-benzothiazole-2-thiolC7H5NS2166.986
    2-Mercaptobenzothiazole, zinc 155-04-4 zinc bis(1,3-benzothiazole-2-thiolate)C14H8N2S4Zn395.886
    2-Mercaptoethanesulfonate, sodium 19767-45-4 sodium 2-mercaptoethanesulfonateC2H7O3S2Na161.942
    6-Mercaptopurine 50-44-2 7H-purine-6-thiolC5H4N4S152.016
    Mercuric chloride 7487-94-7 mercury(2+) dichlorideCl2Hg271.908
    Metepa 57-39-6 1,1',1''-phosphoryltris(2-methylaziridine)C9H18N3OP213.103
    Methafurylene 531-06-6 N-(2-furylmethyl)-N',N'-dimethyl-N-pyridin-2-ylethane-1,2-diamineC14H19N3O245.153
    Methaphenilene 493-78-7 N,N-dimethyl-N'-phenyl-N'-(2-thienylmethyl)ethane-1,2-diamineC15H20N2S260.135
    Methapyrilene.HCl 135-23-9 N,N-dimethyl-N'-pyridin-2-yl-N'-(2-thienylmethyl)ethane-1,2-diamine hydrochlorideC14HN3SCl277.958
    Methimazole 60-56-0 1-methyl-1,3-dihydro-2H-imidazole-2-thioneC4H6N2S114.025
    dl-Methionine 59-51-8 D,L-methionineC5H11NO2S149.051
    Methotrexate 59-05-2 N-{4-[[(2,4-diaminopteridin-6-yl)methyl](methyl)amino]benzoyl}-L-glutamic acidC20H22N8O5454.171
    2-Methoxy-4-aminoazobenzene 80830-39-3 3-methoxy-4-[phenyldiazenyl]anilineC13H13N3O227.106
    3-Methoxy-4-aminoazobenzene 3544-23-8 2-methoxy-4-[phenyldiazenyl]anilineC13H13N3O227.106
    2-Methoxy-3-aminodibenzofuran 5834-17-3 2-methoxydibenzo[b,d]furan-3-amineC13H11NO2213.079
    3-Methoxycatechol 934-00-9 3-methoxybenzene-1,2-diolC7H8O3140.047
    Methoxyphenylacetic acid 1701-77-5 methoxy(phenyl)acetic acidC9H10O3166.063
    8-Methoxypsoralen 298-81-7 9-methoxy-7H-furo[3,2-g]chromen-7-oneC12H8O4216.042
    Z-Methyl-O,N,N-azoxyethane 57497-34-4 [methyl-ONN-azoxy]ethaneC3H8N2O88.064
    Methyl bromide 74-83-9 bromomethaneCH3Br93.942
    Methyl carbamate 598-55-0 methyl carbamateC2H5NO275.032
    Methyl carbazate 6294-89-9 methyl hydrazinecarboxylateC2H6N2O290.043
    Methyl clofenapate 21340-68-1 methyl 2-[(4'-chlorobiphenyl-4-yl)oxy]-2-methylpropanoateC17H17O3Cl304.087
    3'-Methyl-4-dimethylaminoazobenzene 55-80-1 N,N-dimethyl-4-[(3-methylphenyl)diazenyl]anilineC15H17N3239.142
    N-Methyl-N,4-dinitrosoaniline 99-80-9 N-methyl-N,4-dinitrosoanilineC7H7N3O2165.054
    N-Methyl-N-formylhydrazine 758-17-8 N-methylformic hydrazideC2H6N2O74.048
    Methyl hesperidin 11013-97-1 2-(3,4-dimethoxyphenyl)-5-hydroxy-4-oxo-3,4-dihydro-2H-chromen-7-yl 6-O-(6-deoxyhexopyranosyl)hexopyranosideC29H36O15624.205
    Methyl linoleate hydroperoxide 27323-65-5 hydroperoxymethyl octadeca-9,12-dienoateC19H34O4326.246
    Methyl linoleate, native 112-63-0 methyl octadeca-9,12-dienoateC19H34O2294.256
    Methyl methacrylate 80-62-6 methyl 2-methylacrylateC5H8O2100.052
    Methyl methanesulfonate 66-27-3 methyl methanesulfonateC2H6O3S105.972
    N-Methyl-N'-nitro-N-nitrosoguanidine 70-25-7 N-methyl-N'-nitro-N-nitrosoguanidineC2H5N5O3147.039
    2-Methyl-1-nitroanthraquinone 129-15-7 2-methyl-1-nitroanthra-9,10-quinoneC15H9NO4267.053
    4-Methyl-1-[(5-nitrofurfurylidene)amino]-2-imidazolidinone 21638-36-8 4-methyl-1-{[(1E)-(5-nitro-2-furyl)methylene]amino}imidazolidin-2-oneC9H10N4O4238.07
    4-(4-N-Methyl-N-nitrosaminostyryl)quinoline 16699-10-8 N-methyl-N-nitroso-4-[(E)-2-quinolin-4-ylvinyl]anilineC18H15N3O289.122
    N-Methyl-N-nitrosobenzamide 63412-06-6 N-methyl-N-nitrosobenzamideC8H8N2O2164.059
    N-(N-Methyl-N-nitrosocarbamoyl)-l-ornithine 63642-17-1 N~2~-{[methyl(nitroso)amino]carbonyl}-L-ornithineC7H14N4O4218.102

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