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CAS 924-42-5 Properties

MSDS  
: N-Methylolacrylamide
CAS  : 924-42-5
Molecular Formula  
: C4H7NO2
Molecular Weight  
: 101.048
SYNONYMS  : N-(hydroxymethyl)acrylamide

  
MSDS LIST:
  • MSDS Acrylamide, N-(hydroxymethyl)- CAS 924-42-5 MSDS * N-(Hydroxymethyl)acrylamide * N-(Hydroxymethyl)-2-propenamide * N-Methanolacrylamide * N-Methylolacrylamide * Monomethylolacrylamide * NCI-C60333 * 2-Propenamide, N-(hydroxymethyl)- * Uramine T 80
    924-42-5 SYNONYMS   : * N-(Hydroxymethyl)acrylamide * N-(Hydroxymethyl)-2-propenamide * N-Methanolacrylamide * N-Methylolacrylamide * Monomethylolacrylamide * NCI-C60333 * 2-Propenamide, N-(hydroxymethyl)- * Uramine T 80 *** CHEMICAL IDENTIFICATION *** RTECS NUMBER : AS3600000 CHEMICAL NAME : Acrylamide, N-(hydroxymethyl)- CAS REGISTRY NUMBER : 924-42-5 OTHER CAS REGISTRY NOS. : 90456-67-0 BEILSTEIN REFERENCE NO. : 0506646 REFERENCE : 4-02-00-01472 (Beilstein Handbook Reference) LAST UPDATED : 199712 DATA ITEMS CITED : 27 MOLECULAR FORMULA : C4-H7-N-O2 MOLECULAR WEIGHT : 101.12 WISWESSER LINE NOTATION : Q1MV1U1 COMPOUND DESCRIPTOR : Tumorigen Mutagen Reproductive Effector SYNONYMS/TRADE NAMES : * N-(Hydroxymethyl)acrylamide * N-(Hydroxymethyl)-2-propenamide * N-Methanolacrylamide * N-Methylolacrylamide * Monomethylolacrylamide * NCI-C60333 * 2-Propenamide, N-(hydroxymethyl)- * Uramine T 80 *** HEALTH HAZARD DATA *** ** ACUTE TOXICITY DATA ** TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 474 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NEZAAQ Nippon Eiseigaku Zasshi. Japanese Journal of Hygiene. (Nippon Eisei Gakkai, c/o Kyoto Daigaku Igakubu, Konoe-cho, Yoshida, Sakyo-ku, Kyoto 606, Japan) V.1- 1946- Volume(issue)/page/year: 34,183,1979 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 563 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : BCPCA6 Biochemical Pharmacology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1958- Volume(issue)/page/year: 19,2591,1970 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 420 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 1,306,1978 TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 16 gm/kg TOXIC EFFECTS : Behavioral - tremor REFERENCE : ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,111,1990 ** OTHER MULTIPLE DOSE TOXICITY DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 8736 mg/kg/27W-C TOXIC EFFECTS : Behavioral - muscle weakness REFERENCE : BJIMAG British Journal of Industrial Medicine. (British Medical Journal, Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year: 27,147,1970 TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2400 mg/kg/16D-I TOXIC EFFECTS : Related to Chronic Data - death REFERENCE : NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NTP-TR-352,1989 TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3250 mg/kg/13W-I TOXIC EFFECTS : Behavioral - ataxia Kidney, Ureter, Bladder - changes in bladder weight Related to Chronic Data - changes in testicular weight REFERENCE : NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NTP-TR-352,1989 TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 4688 mg/kg/8W-I TOXIC EFFECTS : Related to Chronic Data - changes in testicular weight REFERENCE : AR...
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  • MSDS PAGE: CAS 924-42-5 MSDS ilo_org---icsc1637.asp
    924-42-5 File Name : ilo_org---icsc1637.asp N-METHYLOLACRYLAMIDE 1637 April 2006 CAS No: 924-42-5 N-(Hydroxymethyl)acrylamide RTECS No: AS3600000 N-(Hydroxymethyl)-2-propenamide Monomethylolacrylamide N-Methanolacrylamide C4H7NO2 Molecular mass: 101.1 TYPES OF ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING HAZARD/ EXPOSURE FIRE Combustible. NO open flames. Powder, alcohol-resistant foam, water spray, carbon dioxide. EXPLOSION In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! Inhalation Cough. Sore throat. Local exhaust or breathing protection. Fresh air, rest. Skin Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap. Eyes Redness. Safety goggles or eye protection in First rinse with plenty of water for several combination with breathing protection. minutes (remove contact lenses if easily possible), then take to a doctor. Ingestion Abdominal pain. Do not eat, drink, or smoke during work. Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention. SPILLAGE DISPOSAL PACKAGING & LABELLING Personal protection: P2 filter respirator for harmful particles. GHS classification Do NOT let this chemical enter the environment. Sweep Signal: Warning spilled substance into containers, then remove to safe place. Excl mark-Health haz Harmful if swallowed Causes mild skin irritation Causes eye irritation Suspected of damaging fertility or the unborn child May cause damage to peripheral nervous system through prolonged or repeated exposure Toxic to aquatic life EMERGENCY RESPONSE SAFE STORAGE Separated from acids, Store only if stabilized. Store in an area without drain or sewer access. Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission 漏 IPCS 2006 International Programme on SEE IMPORTANT INFORMATION ON THE BACK. Chemical Safety 1637 N-METHYLOLACRYLAMIDE IMPORTANT DATA Physical State; Appearance Routes of exposure WHITE CRYSTALS. The substance can be absorbed into the body by inhalation and through the skin, and by ingestion. Chemical dangers The substance may polymerize due to heating and under the influence of Inhalation risk acid(s). The substance decomposes on burning producing toxic fumes A harmful concentration of airborne particles can be reached quickly when including nitrogen oxides. dispersed, especially if powdered. Occupational exposure limits Effects of short-term exposure TLV not established. The substance is mildly irritating to the eyes and the skin. The substance MAK not established. may cause effects on the nervous system. Effects of long-term or repeated exposure The substance may have effects on the peripheral nervous system. Animal tests show that this substance possibly causes toxicity to human reproduction or development. PHYSICAL PROPERTIES Boiling point: 277/C Vapour pressure, Pa at 25/C: 0.03 negligible Melting point: 75/C Octanol/water partition coefficient as log Pow: -1.81 calc. Solubility in water, g/100 ml at 20/C: 188 ENVIRONMENTAL DATA The substance is toxic to aquatic organisms. It is strongly advised that this substance does not enter the environment. NOTES An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. ADDITIONAL INFORMATION Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible LEGAL NOTICE for the use which might be made of this information 漏IPCS 2006 ...
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    ALL PAGES On Chemical Properties IN THIS GROUP
    NameCASSynonymsMolecular FormulaMolecular Weight
    R(-)-2-Methyl-N-nitrosopiperidine 14026-03-0 S(+)-2-Methyl-N-nitrosopiperidine(2R)-2-methyl-1-nitrosopiperidine(2S)-2-methyl-1-nitrosopiperidineC6H12N2O128.095
    R(-)-2-Methyl-N-nitrosopiperidine 36702-44-0 S(+)-2-Methyl-N-nitrosopiperidine(2R)-2-methyl-1-nitrosopiperidine(2S)-2-methyl-1-nitrosopiperidineC6H12N2O128.095
    Methyl 12-oxo-trans-10-octadecenoate 21308-79-2 methyl (10E)-12-oxooctadec-10-enoateC19H34O3310.251
    N-Methyl-2-pyrrolidone 872-50-4 1-methylpyrrolidin-2-oneC5H9NO99.068
    (N-6)-Methyladenine 443-72-1 N-methyl-9H-purin-6-amineC6H7N5149.07
    (N-6)-Methyladenosine 1867-73-8 N-methyl-9-beta-L-ribofuranosyl-9H-purin-6-amineC11H15N5O4281.112
    alpha-Methylbenzyl alcohol 98-85-1 1-phenylethanolC8H10O122.073
    4-Methylcatechol 452-86-8 4-methylbenzene-1,2-diolC7H8O2124.052
    3-Methylcholanthrene 56-49-5 3-methyl-1,2-dihydrocyclopenta[ij]tetrapheneC21H16268.125
    alpha-Methyldopa sesquihydrate 41372-08-1 bis(3-hydroxy-alpha-methyltyrosine) trihydrateC20H6N2O11449.997
    N-Methyldopamine,O,O'-diisobutyroylester.HCl 75011-65-3 4-[2-(methylamino)ethyl]-1,2-phenylene bis(2-methylpropanoate) hydrochlorideC17HNO4Cl317.959
    4,4'-Methylene-bis(2-chloroaniline) 101-14-4 4,4'-methylenebis(2-chloroaniline)C13H12N2Cl2266.038
    4,4'-Methylene-bis(2-chloroaniline).2HCl 64049-29-2 4,4'-methylenebis(2-chloroaniline) dihydrochlorideC13H2N2Cl4325.897
    4,4'-Methylene-bis(2-methylaniline) 838-88-0 4,4'-methylenebis(2-methylaniline)C15H18N2226.147
    2,2'-Methylenebis(4-methyl-6-tert-butylphenol) 119-47-1 2,2'-methylenebis(6-tert-butyl-4-methylphenol)C23H32O2340.24
    4,4'-Methylenedianiline.2HCl 13552-44-8 4,4'-methylenedianiline dihydrochlorideC13H2N2Cl2255.96
    Methylguanidine 471-29-4 N-methylguanidineC2H7N373.064
    7-Methylguanine 578-76-7 2-amino-7-methyl-1,7-dihydro-6H-purin-6-oneC6H7N5O165.065
    Methylhydrazine 60-34-4 methylhydrazineCH6N246.053
    Methylhydrazine sulfate 302-15-8 methyldiazanium hydrogen sulfateCH8N2O4S139.989
    Methylhydroquinone 95-71-6 2-methylbenzene-1,4-diolC7H8O2124.052
    1-Methylnaphthalene 90-12-0 1-methylnaphthaleneC11H10142.078
    Methylnitramine 598-57-2 N-nitromethanamineCH4N2O276.027
    4-(Methylnitrosamino)-1-(3-pyridyl)-1-butanol 76014-81-8 4-[methyl(nitroso)amino]-1-pyridin-3-ylbutan-1-olC10H15N3O2209.116
    4-(Methylnitrosamino)-1-(3-pyridyl)-1-(butanone) 64091-91-4 4-[methyl(nitroso)amino]-1-pyridin-3-ylbutan-1-oneC10H13N3O2207.101
    (N-6)-(Methylnitroso)adenosine 21928-82-5 N-methyl-N-nitroso-9-beta-L-ribofuranosyl-9H-purin-6-amineC11H4N6O5300.024
    Methylnitrosocyanamide 33868-17-6 methyl(nitroso)cyanamideC2H3N3O85.028
    N-Methylolacrylamide 924-42-5 N-(hydroxymethyl)acrylamideC4H7NO2101.048
    Methylphenidate.HCl 298-59-9 methyl phenyl(piperidin-2-yl)acetate hydrochlorideC14HNO2Cl249.97
    6-Methylquinoline 91-62-3 6-methylquinolineC10H9N143.074
    8-Methylquinoline 611-32-5 8-methylquinolineC10H9N143.074
    p-Methylstyrene 622-97-9 1-methyl-4-vinylbenzeneC9H10118.078
    Methylthiouracil 56-04-2 6-methyl-2-thioxo-2,3-dihydropyrimidin-4(1H)-oneC5H6N2OS142.02
    Metiapine 5800-19-1 2-methyl-11-(4-methylpiperazin-1-yl)dibenzo[b,f][1,4]thiazepineC19H21N3S323.146
    Metronidazole 443-48-1 2-(2-methyl-5-nitro-1H-imidazol-1-yl)ethanolC6H9N3O3171.064
    Michler's ketone 90-94-8 bis[4-(dimethylamino)phenyl]methanoneC17H20N2O268.158
    Misoprostol 59122-46-2 methyl (11alpha,13E)-11,16-dihydroxy-16-methyl-9-oxoprost-13-en-1-oateC22H38O5382.272
    Mitomycin-C 50-07-7 [(1aS,8S,8aR,8bS)-6-amino-8a-methoxy-5-methyl-4,7-dioxo-1,1a,2,4,7,8,8a,8b-octahydroazireno[2',3':3,4]pyrrolo[1,2-a]indol-8-yl]methyl carbamateC15H2N4O5318.003
    Molybdenum trioxide 1313-27-5 molybdenum trioxideO3Mo145.89
    Monoacetyl hydrazine 1068-57-1 acetohydrazideC2H6N2O74.048
    Monochloroacetic acid 79-11-8 chloroacetic acidC2H3O2Cl93.982
    Monocrotaline 315-22-0 (3S,4S,5R,13aR)-4,5-dihydroxy-3,4,5-trimethyl-4,5,8,10,12,13,13a,13b-octahydro-2H-[1,6]dioxacycloundecino[2,3,4-gh]pyrrolizine-2,6(3H)-dioneC16H23NO6325.152
    Monosodium aspartate 3792-50-5 sodium (2S)-2-amino-3-carboxypropanoateC4H8NO4Na157.035
    dl-Monosodium glutamate 142-47-2 l-Monosodium glutamatesodium 5-oxido-5-oxo-D-norvalineC5H10NO4Na171.051
    dl-Monosodium glutamate 32221-81-1 l-Monosodium glutamatesodium 5-oxido-5-oxo-D-norvalineC5H10NO4Na171.051
    Monosodium succinate 2922-54-5 sodium 3-carboxypropanoateC4H7O4Na142.024
    4-Morpholino-2-(5-nitro-2-thienyl) quinazoline 58139-48-3 4-morpholin-4-yl-2-(5-nitro-2-thienyl)quinazolineC16H14N4O3S342.079
    l-5-Morpholinomethyl-3-[(5-nitrofurfurylidene)amino]-2-oxazolidinone.HCl 3031-51-4 5-(morpholin-4-ylmethyl)-3-{[(5-nitro-2-furyl)methylene]amino}-1,3-oxazolidin-2-one hydrochlorideC13HN4O6Cl343.958
    Myleran 55-98-1 butane-1,4-diyl dimethanesulfonateC6H14O6S2237.961
    Nafenopin 3771-19-5 2-methyl-2-{4-[1,2,3,4-tetrahydronaphthalen-1-yl]phenoxy}propanoic acidC20H22O3310.157

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